Page 5 - Physical chemistry eng
P. 5
Brief Contents
1 Fundamental Concepts of Thermodynamics 1 21 Many-Electron Atoms 483
2 Heat, Work, Internal Energy, Enthalpy, and the 22 Quantum States for Many-Electron Atoms and
First Law of Thermodynamics 17 Atomic Spectroscopy 507
3 The Importance of State Functions: Internal 23 The Chemical Bond in Diatomic
Energy and Enthalpy 45 Molecules 537
4 Thermochemistry 67 24 Molecular Structure and Energy Levels for
Polyatomic Molecules 567
5 Entropy and the Second and Third Laws of
Thermodynamics 85 25 Electronic Spectroscopy 601
6 Chemical Equilibrium 125 26 Computational Chemistry 631
7 The Properties of Real Gases 165 27 Molecular Symmetry 687
8 Phase Diagrams and the Relative Stability of 28 Nuclear Magnetic Resonance
Solids, Liquids, and Gases 181 Spectroscopy 715
9 Ideal and Real Solutions 209 29 Probability 747
10 Electrolyte Solutions 243 30 The Boltzmann Distribution 771
11 Electrochemical Cells, Batteries, and Fuel 31 Ensemble and Molecular Partition
Cells 259 Functions 793
12 From Classical to Quantum Mechanics 293 32 Statistical Thermodynamics 825
13 The Schrödinger Equation 309 33 Kinetic Theory of Gases 857
14 The Quantum Mechanical Postulates 331 34 Transport Phenomena 877
15 Using Quantum Mechanics on Simple 35 Elementary Chemical Kinetics 909
Systems 343
36 Complex Reaction Mechanisms 955
16 The Particle in the Box and the Real
World 361 APPENDIX A Math Supplement 1007
17 Commuting and Noncommuting Operators APPENDIX B Data Tables 1029
and the Surprising Consequences of
APPENDIX C Point Group Character
Entanglement 383
Tables 1047
18 A Quantum Mechanical Model for the
APPENDIX D Answers to Selected End-of-Chapter
Vibration and Rotation of Molecules 405
Problems 1055
19 The Vibrational and Rotational Spectroscopy
CREDITS 1071
of Diatomic Molecules 431
20 The Hydrogen Atom 465 INDEX 1073
iv
