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7/136 Leak Impact Factor
          severe potential consequences are often used as a surrogate for   narios, and it is also has the potential to cause short- and long-
          the distribution in a relative risk model. When absolute risk   term environmental damages.
          values are sought, the consequence distribution must be better   Many products will have some acute hazard characteristics
          characterized as is described in later chapters.   and some chronic hazard characteristics. The evaluator should
            A comprehensive consequence assessment sequence might   imagine where his product would fit on a scale such as that
          follow these steps:                        shown in Figure 7.3, which shows a hypothetical scale to illus-
                                                     trate where some common pipeline products may fit in relation
          1.  Determine damage states of interest (see Chapter 14)   to each other. Aproduct’s location on this scale depends on how
          2.  Calculate hazard distances associated with damage states of   readily it disperses (the persistence) and how much long-term
            interest                                 hazard and short-term hazard it presents. Some product hazards
          3.  Estimate hazard areas based on hazard distances and source   are almost purely acute in nature, such as natural gas. These are
            (burning pools, vapor  cloud centroid, etc.)  location (see   shown on the left edge of the scale. Others, such as brine, may
            particle fmce element inTable 7.6)       pose little immediate (acute) threat, but cause environmental
          4.  Characterize receptor vulnerabilities within the hazard areas   harm as a chronic hazard. These appear on the far right side of
                                                     the scale.
            Limited modeling resources often requires some short cuts
          to this process-leading  the use of screening simplifications   Al.  Acute hazards
          and detailed analyses at only critical points. Such simplifica-
          tions and the use of conservative assumptions for modeling   Both gaseous and liquid pipeline products should be assessed
          convenience,  are discussed in this chapter.   in terms oftheir flammability, reactivity, and toxicity. These are
                                                     the acute hazards. One industry-accepted scale for rating prod-
                                                     uct  hazards  comes  from  the  National  Fire  Prevention
          A.  Product hazard                         Association (NFPA). This scale rates materials based on the
                                                     threat to emergency response personnel (acute hazards).
          The primary factor in determining the nature of the hazard is   If the product is a mixture of several components, the mix-
          the  characteristics of  the  product  being  transported in  the   ture itself could be rated. However, a conservative alternative
          pipeline. It is the product that to a large degree determines the   might be to base the assessment on the most hazardous compo-
          nature of the hazard.                      nent, because NFPA data might be more readily available for
            In studying the impact of a leak, it is often useful to make a   the components individually.
          distinction between acute and chronic hazards.  Acute can mean   Unlike the previous point scoring systems described in this
          sudden onset, or demanding urgent attention, or of short dura-   book, the leak impact factor reflects increasing hazard with
          tion. Hazards such as fire, explosion, or contact toxicity are   increasing point values.
          considered to be acute hazards. They are immediate threats
          caused by a leak.                          Flammabili& Nr
            Chronic means marked by a long duration. A time variable is
          therefore implied. Hazards such as groundwater contamina-   Many  common pipeline products  are very flammable. The
          tion, carcinogenicity, and  other long-term health effects are   greatest hazard from most hydrocarbons is from flammability.
          considered to be chronic hazards. Many releases that can cause   The symbol N, is used to designate the flammability rating of
          damage to the environment are chronic hazards because they   a substance according to the NFPA scale. The five-point scale
          can cause long-term effects and have the potential to worsen   shows, in a relative way, how susceptible the product is to com-
          with the passage of time.                  bustion. The flash point is one indicator of this flammability.
            The primary difference between acute and chronic hazards is
          the amount of time involved. An  immediate hazard, created
          instantly upon initiation of an event, growing to its worst case
          level within a few minutes and then improving, is an acute haz-   Methane   Ammonia   Brine
          ard. The hazard that potentially grows worse with the passage
          of time is a chronic hazard.                       Ethane      Gasoline  Diesel
            For example, a natural gas release poses mostly an acute haz-
          ard. The largest possible gas cloud normally forms immedi-   Propane   Fuel oil
          ately, creating a fire/explosion hazard, and then begins to shrink   Propylene   Toluene
          as pipeline pressure decreases. If the cloud does not find an   Ethylene   Benzene
          ignition source, the  hazard  is  reduced  as  the  vapor  cloud
          shrinks. (If the natural gas vapors can accumulate inside a    Styrene
          building, the hazard may become more severe as time passes-   Oxygen
          it then becomes a chronic hazard.)
            The spill of crude oil is more chronic in nature because the                    1
          potential for  ignition and  accompanying thermal  effects is   Immediate  t
          more remote, but in the long term environmental damages are   only                1
          likely.
            A gasoline spill contains both chronic and acute hazard char-   Figure 7.3  Relative acute-chronic hazard scale for common pipeline
          acteristics. It is easily ignited, leading to thermal damage sce-   products.
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