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Mechanical Behaviour of  Plastics                               59

                                               Table 2.1
                              Qpical tensile and shear moduli for a range of polymers
                                                         Tensile    Shear
                                                        modulus    modulus   Poisson’s
                                               Density    (E)?      (G)      ratio (u)
                           Material            (kg/m3)   (GN/m2)   (GN/mZ)

                 Polystyrene (PS)               1050      2.65      0.99      0.33
                 Polymethyl Methacrylate (PMMA)   1180    3.10      1.16      0.33
                 Polyvinyl Chloride (PVC)
                  (Unplasticised)               1480      3.15      1.13      0.39
                 Nylon 66 (at 65% RH)           1140      0.99      0.34      0.44
                 Acetal Homopolymer (POM)       1410      3.24      1.15      0.41
                 Acetal Copolymer (POM)         1410      2.52      0.93      0.39
                 Polyethylene - High Density (HDPE)   955   1.05    0.39      0.34
                 Polyethylene - Low Density (LDPE)   920   0.32     0.1 1     0.45
                 Polypropylene Homopolymer (PP)   910     1.51      0.55      0.36
                 Polypropylene Copolymer (PP)    902      1.13      0.40      0.40
                 Pol yethersulphone             1390      2.76      0.98      0.41
                                                                              -
                  tl00 second modulus at 20°C for small strains (t0.2%)


                   Note that the ratio of  the ratio of  the hoop stress (pR/h) to the axial stress
                 (pR/2h)  is  only  2.  From  the data in  this  question  the  hoop  stress will  be
                 8.12 MN/m2. A plastic cylinder or pipe is an interesting situation in that it is
                 an example of  creep under biaxial stresses. The material is being stretched in
                 the hoop direction by a stress of  8.12 MN/mz but the strain in this direction is
                 restricted by  the perpendicular axial stress of  OS(8.12) MN/m2. Reference to
                 any solid mechanics text will show that this situation is normally dealt with by
                 calculating an equivalent stress, a,. For a cylinder under pressure a,  is given
                 by OSa&   where a0 is the hoop stress. This would permit the above question
                 to be solved using the method outlined earlier.
                   Example 2.4  A glass bottle of  sparkling water has an acetal cap as shown
                 in Fig. 2.14. If the carbonation pressure is 375 kN/m2, estimate the deflection
                 at the centre of  the cap after 1 month. The value of  Poissons ratio for acetal
                 may be taken as 0.33.
                   Solution The top of the bottle cap is effectively a plate with clamped edges.
                 The central deflection in such a situation is given by Benham et al. as

                                       PP                 Eh3
                                   6 = -
                                             where D =
                                       640             12(1 - v2)
                 To calculate 6 after 1 month it is necessary to know the 1 month creep modulus.
                 The stresses at the centre of the cap are biaxial (radial and circumferential) both
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