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Polymer nanocomposites for water treatments                       573



























           Fig. 21.4 Schematic of nanoscale fillers.


           nanocomposites are synthesized via methods given in Fig. 21.5 [19,20]. On the
           basis of the method and materials used, three types of microstructure can be
           obtained: unintercalated (or microcomposite), intercalated (and/or flocculated), or
           exfoliated (or delaminated), as shown in Fig. 21.6 [21].



           21.5   Polymer nanocomposites—Promising materials
                  for water treatment

           21.5.1 Membranes

           Fig. 21.7 shows a schematic representation of different membrane-based processes
           [22]. Less energy requirement and easy availability of membrane materials make them
           more demanding.
              Polymeric membrane is currently the most widely used membrane for water treat-
           ment, but it is restricted by several challenges such as trade-off relationship between
           permeability and selectivity and low resistance to fouling. Nanocomposite mem-
           branes, a new class of membranes fabricated by combining polymeric materials with
           nanomaterials, are emerging as a promising solution of these challenges. Engineered
           nanomaterials have the potential for the creation of membranes that are optimized to
           meet all the challenges of desalination and wastewater treatment including fouling and
           biofouling while extending the lifetime of the membrane by enhancing their mechan-
           ical robustness and resistance to cleaning regimes [23]. The advanced nanocomposite
           membranes could be designed to meet specific water treatment applications by tuning
           their structure and physicochemical properties and introducing unique functionalities.
           There are following four types of nanocomposite membranes [24]: (1) conventional
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