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38                                                      Chapter 1


             accomplished by two techniques, namely, exploiting AFM to push particles,
             and DIP-Pen lithography.



             1.2.3.6.1 AFM-based Nanomanipulation

               In this technique, an oscillating AFM tip  is brought close to a  particle
             until, as a result of jump-to-contact, the oscillation amplitude goes to zero.
             The AFM approaches the nanoparticle via a fast X-Y scanning oscillation, in
             a plane perpendicular to the desired pushing direction, z, see Figure 1-34.
             Once  contact  of the AFM with  the  nanoparticle is established, motion
             proceeds in the z-direction at a slow scan rate.

                                          Trajectory of Tip in X,Y
                                          Trajectory of Tip in X,Y

                                                     Pushing Direction
                                                     Pushing Direction
                       Fast Scan
                       Fast Scan




                                   Slow Scan
                                   Slow Scan

                        Figure 1-34. Pushing a nanoparticle with AFM.  (After [49].)

             1.2.3.6.2 DIP-Pen Lithography

                 In this technique, developed by Mirkin’s group [50], see Fig. 1-35, and

                         AFM Tip


                                                             Writing
                                                             Direction
                            Molecular
                            Transport
                                                              Water
                                                              Meniscus




                                 Solid Substrate


            Figure 1-35. Close-up of inked AFM tip as molecules flow down the tip via water meniscus.
            (After [50].)
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