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The Electronic System
                                                 1.0  T


                                                 0.5


                Figure 3.7. Transmission proba-
                               E
                            E
                    T
                bility   versus  .   is measured                                    E
                in multiples of V  .                      1       2       3      4
                             0
                                                           T
                             whole incoming wave is transmitted.   also shows pronounced minima
                             for E ≥  V  , which one does not expect in a classical behavior.
                                     0

                             3.2.5 The Harmonic Oscillator

                             In Section 2.4.1 the normal modes of vibration for a lattice were intro-
                             duced. It has been shown that in a first approximation the Hamilton func-
                             tion of the total lattice vibration is a sum of non-interacting harmonic
                             oscillators. The quantization of the lattice vibrations has been presumed
                             in 2.4.1 to explain the discrete nature of phonons. The intercommunity
                             with electrons crops up due to the form of the potential energy.

                Harmonic     U =  mω q ⁄  2  is the potential energy of a linear harmonic oscillator in
                                     2 2
                Oscillator   one dimension. The Hamiltonian for a particle moving in such a potential
                Potential
                             reads

                                                          2
                                                         p ˆ
                                            ˆ
                                                    ˆ
                                                 ˆ
                                                             ----ω q
                                            H =  T +  U =  ------- +  m  2 2      (3.50)
                                                         2m  2
                             The potential energy U goes to infinity as q →  ± ∞  . Therefore, the parti-
                             cles’ wavefunction must go to zero for q →  ± ∞  . The resulting spectrum
                             of the Hamiltonian will be discrete, with energy eigenvalues E   and the
                                                                                n
                                                               ⁄
                             respective eigenfunctions  Ψ =  exp  ( – (  i —)E t)ψ q()  .  The variable
                                                     n             n   n
                             q  denotes the amplitude of the oscillator spring or the position of the
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