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                           Cha p te r
                                    Se v e n

                             An accurate method for the detection of leakage of flammable
                          gases such as methane (CH ), propane (C H ), and ethylene (C H ) is
                                                 4           3  8              2  4
                          vital in gas and petrochemical plants in order to avoid serous acci-
                          dents. The recent introduction of low-loss fiber into spectroscopic
                          measurements of these gases offers many advantages for process
                          control in manufacturing:
                              •  Long-distance remote sensing
                              •  On-line measurement and monitoring
                              •  Low cost
                              •  High reliability

                             The most commonly used method at present is to carry the sam-
                          ple back to the measuring laboratory for analysis; alternatively,
                          numerous spectrometers may be used at various points around the
                          factory. The new advances in spectroscopic measurements allow even
                          CH  to be observed at a distance of 10 km with a detection sensitivity
                             4
                          as low as 5 percent of the lower explosion limit (LEL) concentration.
                          The optical-fiber gas measuring system employs an absorption spec-
                          troscopy technique, with the light passing through a gas-detection
                          cell for analysis. The overtone absorption bands of a number of flam-
                          mable gases are located in the near-infrared range (Fig. 7.37).
                             The optical gas sensing system can deal with a maximum of 30
                          detection cells (Fig. 7.38). The species to be measured are CH , C H ,
                                                                              4  3  8
                          and C H  molecules. Light from a halogen lamp (an infrared light
                                2  4
                          source) is distributed into a bundle of 30 single optical fibers. Each of
                                                  HCI NH CH 4  CO 2  C H
                                                         3
                                                                      2 4
                                           H O  CH 4  NO 2  H O C H    CH 4
                                                                2 2
                                            2
                                                            2
                                           NH 3                 NH 3   C H   H O
                                                                              2
                                                                        3 3
                                  3
                               Silica optical fiber  transmission loss (dB/km)  2



                                  1


                                  0
                                   0.8     1.0     1.2     1.4     1.6     1.8
                                              Wavelength (mm)
                          FIGURE 7.37  Absorption lines of typical fl ammable gases in the near-infrared,
                          and the transmission loss of silica fi ber.
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