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200                                                  Soil and Water Contamination


                     Box 11.III  (continued) Physics of groundwater and soil water flow

                     In the case of saturated groundwater flow, the right-hand side of Equation (11.III.4) can
                     be rewritten as:
                            1  n       h
                            w
                                    S s                                             (11.IIIf)
                            t          t
                       w
                                                 -1
                     where  S  = the specific storage [L ], which is a proportionality constant relating the
                            s
                     changes in water volume per unit change in hydraulic head. Thus, a change in water flow
                     in space results in a change in the hydraulic head. In the case of an unconfined aquifer,
                     the specific storage is equal to the part of the pore volume that can yet be occupied by
                     water. This is often somewhat less than the porosity, because the soil matrix is rarely
                     completely dry. In the case of a confined aquifer, the specific storage is much smaller and
                     depends on the changes in pore volume as result of changes in hydraulic head, and thus
                     on the compressibility of the rock matrix.
                     In the case of unsaturated soil water flow, the right-hand side of Equation (11.III.4)
                     equals:
                            1  w n
                                                                                    (11.IIIg)
                            t        t
                       w
                     which implies that a change in water flow in space results in a change in moisture content
                     of the soil in time.

                     The momentum equation is represented by Darcy’s law, which relates the flow rate to the
                     hydraulic gradient. The one-dimensional form of Darcy’s law for flow in direction x reads:
                                 h
                     q        K                                                     (11.IIIh)
                      x        x
                                 x
                                                      -1
                     where K  = the hydraulic conductivity [L T ], which depends on the grain size distribution
                           x
                     of the soil matrix and varies over several orders of magnitude. The saturated hydraulic
                                                                                  -9
                                                                                       -1
                                               -2
                                                               -5
                                                    -1
                                                                    -1
                     conductivity is in the order of 10  m s  for gravel, 10  m s  for sand, and 10  m s  for
                     clay. In unsaturated conditions, the air in the soil greatly reduces the connectivity of the
                     pores and hence also greatly reduces the hydraulic conductivity. Accordingly, the hydraulic
                     conductivity is a function of soil moisture (and thus of the pressure head).
                     The combination of Darcy’s law (Equation 11.IIIh) and the continuity equation
                     (Equation 11.IIId) yields:
                            h              h             h             1  n
                         K             K             K                 w            (11.IIIi)
                      x   x  x       y   y  y      z   z  z       w    t
                     This equation has numerous analytical solutions for various simplified situations for both
                     groundwater and unsaturated flow. Because unsaturated flow largely consists of vertical
                     drainage driven by gravity forces, unsaturated models are usually one-dimensional. For
                     more complex distributed models, the equations are mostly solved numerically using
                     available model codes, such as MODFLOW (McDonald and Harbaugh, 1988), a widely
                     used three-dimensional finite-difference groundwater flow model.












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