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158   Cha p te r  S e v e n


                     1995) is used to enumerate all the combinatorially feasible process
                     structures that satisfy Axioms (S1)–(S5) or the accelerated branch and
                     bound (ABB) algorithm (Friedler et al., 1996) is used to generate the
                     optimal process structure together with a ranked, finite list of near-
                     optimal structures.
                        Figure 7.5 illustrates the connections among the three
                     algorithms. Algorithm MSG generates the maximal structure, and
                     it can be followed either by algorithm SSG to generate all
                     combinatorially feasible process structures or by algorithm ABB to
                     generate the optimal and near-optimal processes. Algorithms MSG
                     and SSG require as input the list of candidate operating units, each
                     defined by the set of its input materials (preconditions) and
                     products (effects). Algorithm ABB requires, in addition to these
                     data, quantitative information (e.g., prices of raw materials, costs
                     and capacity constraints of operating units) relevant to assessing
                     network optimality.
                        These algorithms and their description are available online
                     (www.p-graph.com). The methodology has been demonstrated via
                     typical engineering decision problems (see Chapter 8 for details). A
                     considerable advantage of the P-graph framework is its potential for
                     solving large industrial problems, as indicated by its application in
                     solving various process systems engineering problems (see, e.g., Liu
                     et al. 2004; Halasz, Povoden, and Narodoslawsky, 2005; Liu et al.,
                     2006; Fan et al., 2008; Varbanov and Friedler, 2008).




                                        Process Synthesis Problem



                                            Algorithm MSG



                                           Maximal Structure






                              Algorithm SSG                Algorithm ABB


                           Combinatorially Feasible
                                                           Optimal Process
                                Structures                (n-best Processes)
                            (for further evaluation)
                     FIGURE 7.5  Inputs to and outputs from the three P-graph algorithms.
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