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166   Cha p te r  E i g h t


                        The issues tackled by PI are essentially complex optimization
                     problems. As a result, optimization is used by PI to answer the
                     question of “how should the task be performed?” The general goals
                     and specific targets are usually achieved by employing optimization
                     tools at various stages. For instance, process performance targets are
                     typically evaluated by employing a numerical technique that involves
                     a cascade of some sort—a heat cascade in the case of heat recovery
                     targeting. One way to implement such cascades is by using the
                     transshipment optimization formulations, where the external utility
                     use, resource intake, or emissions rate is set as the objective function
                     to be minimized. Once the PI goals are established, engineers strive
                     to achieve the best possible performance. In the case of grassroots
                     design or network synthesis, the criterion is minimization of the total
                     annualized cost; in the case of a retrofit, the main criterion may be
                     minimizing the investments necessary to achieve a certain
                     performance improvement or minimizing the payback period for a
                     given investment. For operational improvements, the criteria include
                     minimizing operating costs or maximizing marginal financial or
                     performance gains. In all cases, a certain system model—including
                     the appropriate objective function—is formulated. The model is then
                     subjected to optimization toward the end of achieving (or maximally
                     approaching) the PI targets. Another function of targets is to partition
                     complex optimization problems into sets of simpler problems that are
                     easier to solve. This approach exemplifies the problem decomposition
                     principle, applied for decades in the world of software development,
                     also known as the “divide and conquer” strategy.

                8.2  Optimization Tools for Efficient Implementation of PI

                     For optimizing process models, a wide variety of linear programming
                     (LPR), nonlinear programming (NLP), and mixed-integer programm-
                     ing (MIP) methods can be used, depending on the nature of the
                     problem being solved. Some of these methods were described in
                     Chapters 3 and 7. Special tools and software (see Chapter 9)
                     incorporating optimization methods have been developed to exploit
                     PI possibilities when performing process synthesis, accounting for
                     the interactions between process operating conditions and the
                     networks for resource recovery (energy and water). There are four
                     main groups of optimization tools applied for PI. First, the Pinch
                     Analysis (Linnhoff et al., 1982) enabled industrial engineers to
                     obtain better results with the simple Pinch Design Method than
                     with Mathematical Programming methods in applications to
                     industrial Heat Integration; see Chapter 4. Second, the graph-
                     theoretic method is based on process graphs (P-graphs), which were
                     originally developed for Process Network Synthesis (PNS) (Friedler
                     et al., 1992b; Friedler, Fan, and Imreh, 1998); see Chapter 7. Third,
                     Papoulias and Grossmann (1983) introduced linear constraints in
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