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          STRUCTURAL  AND  THERMAL                          Table 9.1.  Factors Determining Temperature in
          EVOLUTION OF SEDIMENTARY BASINS                   Sedimentary Basin Fill
                                                                               Importance
            Are  the  structural  and  thermal evolution of sedimen­
          tary basins  linked?  In  some cases  the  answer  is  yes, but   Factor   (Order)   Qualifications
          on  the  scale  of  a  petroleum  system,  this  fact  may  have   Overburden thickness  1 s t   Always important
          little  utility  in  attempts  to  understand  the  temperature   Heat flow   1 s t   Always important
          history of the basin fill.  For example, the formation of rift   Thermal conductivity   1 s t   Always important
          basins is well understood through relatively simple theo­  Surface temperature   2nd   Always important
          retical models that invoke an initial extensional event.  In   Sedimentation   1 s t   > 1 0 0 m/m.y.
          these  cases,  it is  possible  to  demonstrate  with  a  fair      2nd           1 0 0 m/m.y.
          amount  of confidence  a  link between the thermal  and              3rd          < 1 0   m/m.y.
          structural  evolution  of these basins.  However,  this may   Groundwater flow
          be of  limited  relevance in estimating temperature of the   Gravity driven   1 s t-2nd   Foreland basins
          basin  fill  at  a  time  when  hydrocarbons  are  being   Compaction driven   3rd   Unless focused
          thermally generated.  The  magnitude  of  the  initial   Free convection   Unknown
          thermal event associated with  the creation of a rift basin   Initial thermal event   1 s t (0-20 Ma)   Rift basins only
          decays with passing time (Figure 9.3). Thus, by the time            2nd (20-60 Ma)
          sufficient  overburden  accumulates  for  hydrocarbon               3rd (>60 Ma)
          maturation  to  begin,  the  influence  of  the initial  basin­
          forming  thermal  event  may  be  relatively  small  in
          comparison to other factors.
            An example of a rift basin in which the initial  thermal   Nevertheless,  steady-state conductive heat transport is a
          event had  little influence on the maturation of hydrocar­  useful first order approximation that  provides  a starting
          bons  is  the  Gulf Coast  basin  of  the  southeastern  United   point  from  which  one  may  later  consider  departures.
          States. This basin formed by riftg in Late Triassic-Early   Fourier's law of heat conduction is
          Jurassic  time  (-180  Ma),  but  it  was  relatively  sediment
          starved  up  to  about 40 Ma.  Rapid  accumulation  of              q = k g                  (2)
          sediments since that time  has  increased the burial depth
          and  temperature  of the  source  rocks.  Cretaceous  and   where q is heat flow, k is  thermal  conductivity,  and g is
          early Tertiary age source rocks are estimated to presently   the  thermal  gradient. Applying this  to  the  analysis  of
          be  in  the  oil  generation  window  (N unn  and  Sassen,   temperature within sedimentary basins, we obtain
          1986).  Because  the thermal  anomaly associated with the
          rifting of the  Gulf Coast basin has been decaying  for  the    T = T0 + (q/k) dz:           (3)
          last  180 m.y.,  the  degree  to  which  the  lithosphere  was
          extended  or  rifted  has  a  negligible  influence  on  the   where  T is  subsurface  temperature,  T 0  is  the  mean
          present-day thermal  state  (Figure  9.3).  Factors  such  as   annual  surface  temperature,  and ru:  is  thickness  of  the
          lateral  variations  in  overburden  thickness  and  the   overburden.  Thus,  heat  flow,  thermal conductivity,  and
          depression of heat flow by sedimentation have a greater   overburden thickness  are  of equal importance  in  deter­
          influence  on  source  rock  temperature.  For  example,   mining  subsurface  temperature.  However,  heat  flow  is
          Nunn and Sassen  (1986)  estimate that present-day  heat   generally  a  more  useful  measure  of the  thermal  state  of
          flow in the Gulf Coast basin is depressed -30% below its   sedimentary  basins  than  temperature  gradient  alone
          equilibrium value by high rates of sedimentation.   because  the  geothermal  gradient, g =  (q/k), varies
            On the scale of the petroleum system, the influence of   according to thermal conductivity,  which can change by
          initial basin-forming thermal events is thus of indirect or   as much  as factor of three or four  among common  rock
          limited  importance  in  determining  temperature  of the   types.
          basin  fill  at  the  time  hydrocarbons  are  generated.   A  more generalized description of heat  transport can
          Temperature of the  sedimentary basin fill is  more  likely   be obtained by considering departures from steady-state
          to  be  sensitive  to  intrabasin  factors  such  as  thermal   conditions  and  including  advection  of heat  by  moving
          conductivity,  groundwater  flow,  sedimentation,  and   fluids.  The  change  of  temperature  with  respect  to  time
          surface  temperature (Table 9.1). The  following  sections   (()T /ot) is then described by
          discuss  the  importance  of  these  four  factors  in  more
          detail.                                             pC(oT /ot) = o/oz[kz (oT /oz)] - Vz P wCw (()T /oz)  A  *
                                                                                                    +
                                                                                                       (4)
          MATHEMATICAL DESCRIPTION OF
          HEAT TRANSPORT                                    where z is depth, p and C are the bulk density and heat
                                                            capacity,  respectively,  of  a  porous  rock,  P w  is  fluid
            Sedimentary  basins  are  never  in  complete  thermal   density, Cw is fluid heat capacity, Vz is the Darcy velocity
          equilibrium,  and  groundwater  flow  may  drastically   of  a  fluid  moving  through  a  porous  medium, k2  is
          change the distribution of thermal energy within a basin.   thermal  conductivity,  and  A* is  radioactive  heat genera-
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