Page 272 - Thermodynamics of Biochemical Reactions

272 Mathernatica Solutions to Problems

{{273.15, 1.0751, {283.15, 1.2131, I293.15, 1.38451, (298.15,
{303.15, 1.57751, {313.15, 1.811

TableForm Idatah]
273.15 1.075
283.15 1.213
293.15 1.3845
298.15 1.4775
303.15 1.5775
313.15 1.8

coefh

(b) Fit the Clarke and Glew enthalpy coefficients

coefh=Fit Idatah, {tA2,tA3},tl
2 -7 3
-0.0000132345 t + 1.0045 10 t
Note -1.28466* 1OA-5+9.9O398* 10A-8tA3 in (a),

coefh/.t->{273.15,283.15,293.15,298.15,303.~5,313.15}

{1.05973, 1.21928, 1.39324, 1.48582, 1.58223, 1.78684)

These values can be compared with the table in (a).