Page 294 - Thermodynamics of Biochemical Reactions

294 Matliematica Solutions to Problems

;
g5x3xlxa = calcrow[mannose +de fructose, 7.6, -02, ~~mannose=fructose~']
:E
gsx4x2x2 =
calcrow[glucoselphos +de == glucose6phos, 8.48, .l, ~1glucoselphos=glucose6phos~~];

g5x4x2x7 =calcrow[riboselphos+de =:ribose5phos, 7, .25, ~~riboselphos=ribose5ghos"l;
g6x2xlxl= calcrow[atp+acetate+coA+de == amp+ppi+acetylcoA,
7, .25, "atp+acetate+coA=amg+ppicacetylcoA~l] ;
g6x3xlx2 = calcrow[atp + glutamate + ammonia + de := adp +pi + glutmine,
;
7, -3, llatp+glutamate+ammonia=adp+pi+glutaminel']
g6x4xlx1 = calcrow [atp + pyruvate + co2tot + de EE adp +pi + oxaloacetate,
7.4, .02, ~~atp+pyruvate+co2tot=adp+pi+oxaloacetate~'];
TableFonn [ {glxlxlxl, glxlxlx26, glxlxlx27b, glxlxlx37, glxlxlx39, glxlxlx40, glxlxlx42,
glxlxlx67, glxlxlx79, glxlX99x7, glx2xlx2, glx2xlx101 glx2xlx43, glx4Xlx1,
glx6xlxlr g1~6~4~2, g1~6~4~5, g2~3X1X54, g2~4~1~7,
g1~4~1~2, g1~4~1~3, gl~4~l~lO
g2x4xlx8, g2x4x2x1, g2x6xlx1, g2x6xlx2, g2x6x1x35, g2x7xlx1, g2x7xlx23, g2x7x4x3,
g3xlx3x1, g3xlx3xlb, g3xlx3xlc, g3x1x3x1df g3xlx3xle, g3x2xlx3, g3x2xlx23,
g3~2~2~4, g3~2~2~7, g3~5~1~2, g4~1~3~1, g4~1X3~6, g4X1X3X7, g4XlX99X1, gdX2XlX2,
g4x2xlx3, g4x3xlx1, g5x3xlx5, g5x3x1x5bl g5x3xlx7, g5x3xlx9, g5x3xlx15,
g5x3xlx20, g5x3xlxa, g5x4x2x2, g5x4x2x7, g6x2xlx1, g6x3xlx2, g6x4xlxl},
TableHeadings + {{mll.l.l.lll, m11.1.1.26m1, 111.1.1.27b", "1.1.1.37", "1.1.1.39",
"1.1.1.40", "1.1.1.42", "1.1.1.67", "1.1.1.79", "1.1.99.7", "1.2.1.2",
1.2.1. loi*, 1.2.1.43", 1.4.1. lit, 1.4.1.2 n, n 1.4.1.3", 1.4.1. lori, "1.6.1. l",
I* 1.6.4 .2 'I, 1 .6.4.5 11, 2 .3 .1.54", 1- 2 .4 . 1 .7 'I, 18 2 .4.1.8 11, 2 -4.2- 1 11 2 .6.1. l",
"2.6.1.2", 1i2.6.1.35in, 112.7.1.111, "2.7.1.23". ii2.7.4.3ii, "3.1.3 .l", "3 .l. 3 .lb",
"3.1.3.1~" , "3.1.3. ld", "3.1.3. le", "3.2.1.3", "3 .2.1.23", "3.2.2.4",
n 3.2.2.7 'I, 1~3.5.1.2*', 1'4.1.3. l", 4.1.3.61'~ 4.1.3.7 It 4.1.99. l", I* 4.2.1.2",
11 4.2.1.3 11, 1~4.3.1.1" , 5.3 . 1 -5 'I, "5 .3.1.5bi*, 5 .3 -1.7 I@, In 5.3 . 1 -9 "5 .3 . 1 .15",
"5.3.1.2 0 , l1 5.3.1. aim, 5.4.2.2 'I, In 5.4.2.7". 6.2.1.1 " , "6.3 . 1 .2", 'I 6.4.1.1" } ,
{llReactionpl, "Calc G1ll}}, Tablespacing -> {I, l}]
Reaction Calc G'
1.1.1.1 ethanol+nadox==acetaldehyde+nadred 22.095

1.1.1.26 glycolate+nadox=gloxylate+nadred 38.896
1.1.1.27b lactate+nadox=pyruvate+nadred 26.3652
1.1.1.37 malate+nadox=oxaloacetate+nadred 28 -2639
1.1.1.39 malate+nadox+h2o=pyruvate+nadred+co2tot 4.45812

1.1.1.40 malate+nadpox+h2o=pyruvate+nadpred+co2tot 1.71088
-3.83041
1.1.1.42 citrateiso+nadpox+h2o=ketoglutarate+nadpred+co2tot
1.1.1.67 mannitolD+nadox=fructose+nadred 1.88013
1.1.1.73 glycolate+nadpox=glyoxylate+nadpred 38.2358

1.1.99.7 lactate+oxaloacetate=malate+pyruvate -4.92266
1.2.1.2 formate+nadox+h2o=co2tot+nadred -15.1398
1.2.1.10 acetaldehyde+coA+nadox=acetylcoA+nadred -13.861
1.2.1.43 formate+nadpox+h2o=co2tot+nadpred -20.4151
1.4.1.1 alanine+nadox+h2o=pyruvate+nadred+monia 29.9682