Page 296 - Thermodynamics of Biochemical Reactions

296 Mathernatica Solutions to Problerns

5.3.1.9 glucose6phos=fructose6phos 3.14096
5.3.1.15 lyxose=xylulose 2.99
5.3.1.20 ribose=ribulose 2.85
5.3.1.a mannose=fructose -5.51

5.4.2.2 glucoselphos=glucose6phos -7.06836
5.4.2.7 riboselphos=ribose5phos -8.08
6.2.1.1 atp+acetate+coA=amp+ppi+acetylcoA -5.97683
6.3.1.2 atp+glutamate+ammonia=adp+pi+glutamine -22.6469

6.4.1.1 atp+pyruvate+co2tot=adp+pi+oxaloacetate -10.7687
(b) Make a table of the relevant data in the Goldberg and Tewari Tables. First make a vector of the experimental apparent
equilibrium constants.

gHvector={7.0,7.8,6.8,7.1,6.5,7.0,6.9,8.05,7.92,7.8,6.2,7.3,7.5,7.97,6.9,7.~,6.4,7.5,6.
9,7.0,7.2,8.25,7.0,7.0,7.4,7.4,7.1,6.07,6.1,7.41,8.86,8.4,6.99,7.0,7.0,5.0,5.65,8.0,7.0
,5.5,7.7,7.0,7.05,7.97,7.3,7.4,7~37,7~5,8.7,7.0,8.7,7.0,7.4,7.6,8.48,7.0,7.0,7.0,7.4~;
isvector={.25,.03,.05,.25,.05,.25,.25,.05,.1,.1,.07~.03~.1~.1~.24~~~~~~~~~~~~~~~~~~~~~~
,.1,.1,.1,.1,.5,.1,.1,~1~.04~~3~~24~~25~~1~~1~~01t~1~~1~~1~~1~~1~~~~~~~~~~~~~~~~~~~~~~~
,.1,.05,.3,.06,.04,.02,.1,.25,.25,.3,.02}
{0.25, 0.03, 0.05, 0.25, 0.05, 0.25, 0.25, 0.05, 0.1, 0.1, 0.07, 0.03, 0.1, 0.1, 0.24, (
0.1, 0.1, 0.1, 0.5, 0.1, 0.1, 0.1, 0.04, 0.3, 0.24, 0.25, 0.1, C.l, 0.01, 0.1, 0.1, 0.
0.1, 0.1, 0.1, 0.05, 0.3, 0.06, 0.04, 0.02, 0.1, 0.25, 0.25, 0.3, 0.02)

calcgvector=~glxlxlxl,glxlxlx26,glxlxlx27b,glxlxlx37 .glxlxlx39, glxlxlx40, glxlxlx42, glxl
x1x67,g1x1x1x79,glxlx99x7,g1x2x1x2,g1x2x1X10,g1x2x1x43,g1x4x1x1,g1~4x1x2,g1~4~1~3,g1~4~
lxlO,glx6xlxl,glx6x4x2, glx6x4x5, g2x3x1x54,g2x4x1x7 ,g2~4~1x8,g2~4~2~1, g2x6xlx1, g2x6xlx2,
g2~6~1~35,g2~7~1x1,g2x7xlx23,g2~7~4~3,g3xlx3xl,g3xlx3xlb,g3xl~3xlc,g3xlx3xld,g3xlx3xle,
g4x2
g3x2xlx3, g3x2xlx23, g3x2x2x4, g3x2x2x7, g3x5xlx2, g4xlx3x1, g4xlx3x6, g4xlx3x7, g4~1~99~1,
~1x2, g4x2xlx3, glx3xlx1, g5x3xlx5, gSx3xlx5b, g5x3xlx7, g5x3xlx9, g5x3xlx15, g5~3~1~20, g5~3~1x
tlA11,211
a,g5x4x2x2,g5x4x2x7,g6~2~lxl,g6~3~1~2~~6~4~1~~l
{22.095, 38.896, 26.3652, 28.2639, 4.45812, 1.71088, -3.83041, 1.88013, 38.2358, -4.9221
38.7895, 36.5242, 51.8996, -0.891743, 6.01048, 6.86709, 11.0295, -11.5121, -1.06837, 2
-20.0611, -8.32968, 2.7092, -12.9696, -13.6567, -11.6294, 1.78075, -23.15, -19.92, -2C
-0.531653, 3.2174, -45.0692, 22.7596, -3.60654, 8.42485, 12.2178, 0.39, 4.34, -5.51, ?
-8.08, -5.97683, -22.6469, -10.7687)