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§14.5  Heat Transfer  Coefficients  for  Forced Convection Through Packed Beds  441

     |14.5  HEAT TRANSFER COEFFICIENTS FOR FORCED
            CONVECTION THROUGH PACKED BEDS
                           Heat transfer  coefficients  between  particles and  fluid  in packed beds  are important in the
                           design  of  fixed-bed  catalytic reactors, absorbers,  driers, and pebble-bed  heat  exchangers.
                           The  velocity  profiles  in  packed  beds  exhibit  a  strong  maximum  near  the wall, attribut-
                           able  partly  to the higher  void  fraction  there and  partly  to the more  ordered  interstitial
                           passages  along  this  smooth boundary.  The resulting  segregation  of  the  flow  into  a  fast
                           outer stream and a slower  interior one, which  mix  at the exit  of  the bed, leads  to compli-
                           cated behavior  of  mean Nusselt numbers  in deep packed  beds, 1  unless  the tube-to-parti-
                           cle diameter  ratio D/D p  is  very  large  or  close  to unity. Experiments with  wide,  shallow
                                           t
                           beds  show  simpler behavior  and are used  in the following  discussion.
                              We  define  ft loc  for  a representative  volume  Sdz of  particles and  fluid  by  the  following
                           modification  of  Eq. 14.1-5:

                                                      dQ  = h (aSdz)(T 0  -  T )               (14.5-1)
                                                                        b
                                                            ]oc
                           Here a is the outer surface  area  of particles per unit bed volume, as in §6.4. Equations  6.4-
                           5 and 6 give the effective  particle size D p  as 6/a v  = 6(1  — s)/a  for  a packed bed with  void
                           fraction  s.
                              Extensive  data on forced  convection for  the flow of gases  and liquids 3  through shal-
                                                                              2
                           low  packed beds have been critically  analyzed 4  to obtain the following  local heat  transfer
                           correlation,
                                                              2/3
                                                   j  = 2.19 Re~  + 0.78  Re'  0 3 8 1         (14.5-2)
                                                   H
                           and  an  identical  formula  for  the  mass  transfer  function  j  D  defined  in  §22.3.  Here  the
                           Chilton-Colburn j H  factor and the Reynolds number are defined  by
                                                                     2/3
                                                                                               (14.5-3)

                                                             D G    _  6G
                                                               p  0     0
                                                           (1   )ф    п(лф                     (14.5-4)

                           In  this  equation  the  physical  properties  are  all  evaluated  at  the  film  temperature  T  =
                                                                                                  f
                           \{T  -  T ), and  G  = zv/S is the superficial  mass flux introduced in §6.4. The quantity  ф is
                                 b
                                         o
                             Q
                           a particle-shape factor, with  a defined  value  of  1 for spheres and a fitted  value 4  of  0.92  for
                                                                                5
                           cylindrical  pellets. A related shape  factor  was  used  by  Gamson  in Re and j ;  the present
                                                                                         H
                           factor  ф is used  in Re only.
                              For  small  Re, Eq. 14.5-2 yields  the asymptote
                                                    j H  = 2.19 Re~  2/3                       (14.5-5)
                           or
                                                  Nu                        1/3
                                                   ioc  = 77,  T "  = 2.19(RePr)               (14.5-6)
                                                         k{\  -  е)ф
                               H. Martin, Chem.  Eng.  Sci., 33, 913-919  (1978).
                              1
                              2
                               B. W. Gamson, G. Thodos, and O. A. Hougen, Trans. AIChE,  39,1-35  (1943); C. R. Wilke and O. A.
                           Hougen, Trans. AIChE, 41, 445-451  (1945).
                               L. K. McCune and  R. H. Wilhelm,  Ind. Eng.  Chem., 41,1124-1134  (1949); J. E. Williamson,  К. Е.
                              3
                           Bazaire, and C. J. Geankoplis, Ind. Eng.  Chem. Fund., 2,126-129  (1963); E. J. Wilson  and C. J. Geankoplis,
                           Ind. Eng.  Chem. Fund., 5, 9-14  (1966).
                              4
                               W.  E. Stewart, to be submitted.
                               B. W. Gamson, Chem.  Eng. Prog., 47,19-28  (1951).
                              5
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