Page 169 - Characterization and Properties of Petroleum Fractions - M.R. Riazi

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3. CHARACTERIZATION OF PETROLEUM FRACTIONS 149
The specific gravity (at 60/60 F ) of fraction is 0.8597
◦
Petroleum Fractions with Pseudocritical Constants,”
[46]. Predict the following properties for the product [10] Zhou, P., “Correlation of the Average Boiling Points of
and compare with reported values. International Chemistry Engineering, Vol. 24, 1984, pp. 731–742.
a. Kinematic viscosities at 100, 140, and 210 F (experi- [11] Daubert, T. E., “Property Predictions,” Hydrocarbon Processing,
◦
mental values are 3.26, 2.04, and 1.12 cSt.) March, 1980, pp. 107–112.
b. Molecular weight from viscosity and compare with [12] Van Winkle, M., “Physical Properties of Petroleum Fraction,”
Petroleum Refiner, Vol. 34, No. 6, 1955, pp. 136–138.
molecular weight estimated from the boiling point. [13] Nelson, W. L. and Hansburg, M., “Relation of ASTM and True
c. Boiling point and specific gravity from experimen- Boiling Point Distillations,” Oil & Gas Journal, Vol. 38, No. 12,
tal values of kinematic viscosities at 100 and 210 F 1939, pp. 45–47.
◦
(Part a) and compare with actual values. [14] Edmister, W. C. and Pllock, D. H., “Phase Relations for
d. Aniline point (experimental value is 143.5 F) Petroleum Fractions,” Chemical Engineering Progress, Vol. 44,
◦
e. Cetane number (experimental value is 43.2) 1948, pp. 905–926.
f. Freezing point (experimental value is 21 F) [15] Edmister, W. C. and Okamoto, K. K., “Applied Hydrocarbon
◦
g. Flash point (experimental value is 230 F) Thermodynamics, Part 12: Equilibrium Flash Vaporization
◦
h. Carbon-to-hydrogen weight ratio (experimental value Correlations for Petroleum Fractions,” Petroleum Refiner,
Vol. 38, No. 8, 1959, pp. 117–132.
is 6.69) [16] Edmister, W. C. and Okamoto, K. K., Applied Hydrocarbon
i. Aromatic content from experimental viscosity at Thermodynamics, Gulf Publishing, Houston, TX, 1961,
100 F (experimental value is 34.9) pp. 116–133.
◦
j. Aromatic content from experimental aniline point [17] Edmister, W. C. and Okamoto, K. K., “Applied Hydrocarbon
(experimental value is 34.9) Thermodynamics, Part 13: Equilibrium Flash Vaporization
k. Refractive index at 75 F (experimental value is Correlations for Heavy Oils Under Subatmospheric Pressures,”
◦
1.4759) Petroleum Refiner, Vol. 38, No. 9, 1959, pp. 271–288.
2
3.25. A vacuum residue has kinematic viscosity of 4.5 mm /s [18] Okamoto, K. K. and van Winkle, M., “Equilibrium Flash
at 100 C and specific gravity of 0.854. Estimate viscosity Vaporization of Petroleum Fractions,” Industrial and
◦
index (VI) of this fraction and compare with reported Engineering Chemistry, Vol. 45, 1953, pp. 429–439.
value of 119 [24]. [19] House, H. G., Braun, W. G., Thompson, W. T. and Fenske,
3.26. A kerosene sample has boiling range of 180–225 C and M. R., “Documentation of the Basis for Selection of the
◦
Contents of Chapter 3, ASTM, TBP, and EFV Relationships for
specific gravity of 0.793. This product has aromatic Petroleum Fractions in Technical Data Book-Petroleum
content of 20.5%. Predict smoke point and freezing Refining,” Documentation Report No. 3-66, Pennsylvania State
point of this product and compare with the experi- University, 1966.
mental values of 19 mm and −50 C [24]. How much [20] Arnold, V. E., “Microcomputer Program Converts TBP, ASTM,
◦
2-methylnonane (C 10 H 22 ) with freezing point of −74 C EFV Distillation Curves,” Oil & Gas Journal, Vol. 83, No. 6,
◦
should be added to this kerosene to reduce the freezing 1985, pp. 55–62.
point to −60 C. [21] Ford, D. C., Miller, W. H., Thren, R. C. and Wertzler, R.,
◦
Correlation of ASTM Method D 2887-73 Boiling Range
Distribution Data with ASTM Method D 86-67 Distillation Data,
STP 577, ASTM International, West Conshohocken, PA, 1973,
REFERENCES p. 29.
[22] Riazi, M. R. and Daubert, T. E., “Analytical Correlations
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Temperature Fused Silica Wide-Bore Columns,” J. High Manual for Computer Software, HYSYS Conceptual Design,
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Mc-Graw Hill, New York, 1999. Industrial and Engineering Chemistry, Vol. 47, 1955,
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Engineering Chemistry, Vol. 29, 1937, pp. 1408–1414. Petroleum Fractions, Doctoral Dissertation, Department of

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