Page 423 - Characterization and Properties of Petroleum Fractions - M.R. Riazi

P1: JsY
AT029-Manual
AT029-INDEX
INDEX 403
Fugacity, 187–188, 237–238, 253,
H
382–383 AT029-Manual-v9.cls March 12, 2007 16:37 Hydrogen, prediction in petroleum
fractions, 127
asphaltene, 386 Hall-Yarborough method, 63 Hydrogen sulfide, equilibrium ratios, 283
calculation from Lewis rule, 256 Hammerschmidt equation, modified, 390
coefficient, mixtures, 254–255 Hard-sphere fluids, entropy departure, I
liquids, 268 286–287
mixtures, 254–255 Hard-sphere potential, 202 Ideal gas
pure gases and liquids, 256–257, 268 Heat capacity, 12, 235 mixture, heat capacity, 244
of solids, 261–263 estimation from refractive index, 321–322 thermodynamic properties, 241–247
Fugacity coefficients, 12, 238 ideal gas, constants, 246–247 Ideal gas law, 203, 209
calculation from equations of state, mixture, 250 In-situ alteration, 2
255–256 thermodynamic properties, 319–321 Infrared spectroscopy, 97
Fusion curve, 200 Heat capacity coefficients, 320 Intensive property, 198–199
Fusion line, 251 Heat capacity ratio, 235 Interfacial tension, see Surface/interfacial
Heat of combustion, 12, 324–326 tension
Heat of formation, 12 Intermolecular forces, 43, 202–203
G Heat of fusion, 201, 259–261 Internal energy, 199
Heat of mixing, 249 IP 2/98, 144
Gamma density function, molar Heat of reaction, 12 IP 12, 144
distribution, 168–169 Heat of sublimation, 314 IP 13/94, 144
Gamma distribution model, 167–170 Heat of vaporization, 12, 201, 252, 321–324 IP 14/94, 144
Gas chromatography, 96–97 at boiling point, 323 IP 15, 135, 144
simulated distillation, petroleum Heating value, 25, 324–326 IP 16, 136, 144
fractions, 89–91 Heats of phase changes, 321–324 IP 34/97, 144
Gas condensate system Heavy hydrocarbons IP 57, 142
C 7+ fraction characteristics, 171 API gravity and viscosity, 59–60 IP 61, 99
pseudocritical properties, 160–161 atmospheric critical pressure, 51 IP 69/94, 144
SCN group prediction, 166–167 boiling point, 50, 52 IP 71/97, 144
Gas constant, 22, 24 constants, 50–51, 54 IP 107, 99, 144
Gas injection projects, 390–391 critical pressure, 52–53 IP 123/99, 144
Gas mixtures critical temperature, 52–53 IP 156/95, 144
properties, 120 prediction of properties, 50–54 IP 196/97, 144
viscosity, 335 refractive index and viscosity, 44 IP 218, 138
Gas phase, 200 Heavy petroleum fractions IP 219, 135, 144
Gas solubility, in liquids, 266–269 enthalpy, 316 IP 236, 144
see also Vapor-liquid equilibria molecular weight and composition, 116 IP 365, 93, 144
Gas-to-liquid ratio, 337–338 Helmholtz free energy, 235 IP 370/85, 144
Gas-to-oil ratio, 368–370 Henry’s constant, 267, 269 IP 380/98, 144
units, 24 Henry’s law, 266–269 IP 402, 131
Gases Heptane, equilibrium ratios, 279 IP 406/99, 144
density, 300 Hexane ISO 2049, 144
diffusivity equilibrium ratios, 278 ISO 2185, 144
at high pressures, 348–350 vapor pressure, 311 ISO 2192, 144
low pressures, 346–347 n-Hexatriacontane ISO 2592, 34
thermal conductivity, 339–342 acentric factor, 65 ISO 2719, 144
Gasoline, characteristics, 143 critical properties, 64 ISO 2909, 123
Gaussian quadrature approach, splitting, High performance liquid chromatography, ISO 2977, 144
185–186 97 ISO 3007, 144
Gel permeation chromatography, 94 High-shrinkage crude oil, 6 ISO 3013, 144
Generalized correlation, 215 Hoffman correlation, 271–272 ISO 3014, 142
Generalized distribution model, Hydrate inhibitors, 389–390 ISO 3015, 135, 144
170–184 Hydrates, formation, 388–390 ISO 3016, 135, 144
boiling point, 178 Hydrocarbon-plus fractions, 153, 164–184 ISO 3104, 100, 144
calculation of average properties, boiling point and specific gravity ISO 3405, 144
175–177 prediction, 173 ISO 3837, 144
subfractions, 177–178 calculation of average properties, ISO 4262, 144
C 6+ fraction, 180 175–177 ISO 4264, 144
C 7+ fractions, 179–180 exponential model, 165–167 ISO 5163, 144
model evaluations, 178–180 gamma distribution model, 167–170 ISO 6615, 144
prediction using bulk properties, general characteristics, 164–165 ISO 6616, 144
181–184 generalized distribution model, 170–184 ISO 6743/0, 10
probability density function, 174–175 molar distribution, 167, 172–173 ISO 8708, 144
specific gravity, 179 molecular weight variation, 165 ISO 12185, 93
versatile correlation, 170–174 prediction of PDF, 173–174 Isofugacity equations, 383
Gibbs energy, 263 probability density functions, 164–165 Isoparaffins, 3
binary system, 263–264 subfractions, calculation of average Isothermal compressibility, 236
excess, 257–258 properties, 177–178
Gibbs free energy, 12, 235 Hydrocarbons, 3–5
Gilliland method, 347 groups, 3 J
Glaso’s correlation, 338 liquid specific gravity, temperature
Glossary, ASTM definitions, 397–400 effect, 301 Jenkins-Walsh method, 128–129
Goossens correlation, 57–58 pure, see Pure hydrocarbons Jet fuel
Goossens method, 127–128 research octane number, 140 characteristics, 143
Grouping, 184 Hydrodynamic theory, 347 enthalpy, 318

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