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144  A COmPREHEnSIVE GuIdE TO SOlAR EnERGy SySTEmS



             to the deployment of CSTP plants. nevertheless, the proven ability of CSTP plants to store
             energy is something that PV plants can’t offer.
                most of the current R + d efforts related to CST technologies are guided by this need to
             reduce costs and also the need to improvement overall efficiency.
                Concerning PTC technology,  the two main R  +  d technology  trends  being
             investigated are: new working fluids for the solar field; and new collector designs. The
             replacement of the thermal oil currently used as working fluid in the solar field by
             silicone-based oils would not only allow higher steam temperatures for the PCS (and
             therefore, higher plant efficiencies), but also less operation and maintenance costs
             due to the lower environmental hazard of silicone oils. The use of molten salt, water/
             steam and compressed gases as working fluids for PTC is also under investigation and
             the advantages and disadvantages of these three innovative working fluids have been
             analysed by Zarza [10].
                The development of new PTC designs with higher concentration ratios is also being
             researched, as it would create a temperature increase in the solar field without increasing
             the thermal losses. Achievement of higher concentration ratio requires mirrors with better
             optical properties as well as sun tracking systems with a higher accuracy.
                Concerning central receiver technology, the main technology trends are related to new
             working fluids to achieve higher temperatures and therefore higher efficiencies. In some
             cases, the new working fluids investigated demand a re-design of the main plant compo-
             nents (i.e., central receiver, thermal storage system, and PCS). new working fluids under
             investigation are:

             –  molten salts suitable for temperatures higher than 600°C
             –  falling particles
             –  supercritical CO 2 , and
             –  atmospheric or compressed air
                molten salt currently used in CSTP plants is composed of a binary mixture of potas-
                                                                                       −1
             sium nitrate (40%) and sodium nitrate (60%). This mixture is cheap (about €1 kg ) and
             it has good thermal stability up to 600°C. new salt compositions are required to increase
             the thermal stability up to 700°C or more, while keeping a moderate melting point and low
             viscosity in the liquid phase.
                The use of small solid particles, with a diameter of 1–2 mm, carried by an air stream is
             also being investigated as an option to increase the working temperature to temperatures
             above 600°C and hence to increase the efficiency of CSTP plants [17]. The solid particles
             heated in the receiver can then be stored in a thermally insulated vessel to be used later
             on when solar radiation is not available. The main challenges when using a falling particle
             receiver are the erosion produced by the friction of the particles inside the piping and ves-
             sels, and the stability of the particles after many heating-cooling cycles. Transport of the
             particles from one component to another is also a technical constraint because conven-
             tional blowers or pumps can’t be used for this purpose.
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