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Chapter 7 • Concentrating Solar Thermal Power  145



                   The feasibility of supercritical CO 2 , (s-CO 2 ), is also being investigated to increase the
                 efficiency of CSTP plants with central receiver technology because it would allow higher
                 working temperatures in the receiver and the Rankine cycle of the PCS could be replaced
                 by a Brayton cycle resulting in higher efficiencies [18]. Because s-CO 2  has good thermo-
                 physical properties as a heat carrier medium, a significant effort is being devoted to using
                 it by R + d centres, located in countries such as the united States of America and Australia.
                 The density of s-CO 2  is similar to that of liquid water and allows for the pumping pow-
                 er needed in a compressor to be significantly reduced, thus increasing the thermal-to-
                 electric energy conversion efficiency of the Brayton cycle. This is the main reason why
                 the use of s-CO 2  is one of the key R + d topics included in the American SunShot initiative
                 (https://energy.gov/eere/sunshot/sunshot-initiative), which is a national effort support-
                 ed by the uS department of Energy to drive down the cost of solar electricity and support
                 the use of solar energy to replace fossil fuels. The target of SunShot for CSTP plants is to
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                 lower the cost of STE to $0.06 (kW h) . At present, the main short-term challenge in this
                 technology program is the implementation of a small (≤10 mW e ) experimental plant using
                 a Brayton cycle with s-CO 2 . Such a plant requires the design and manufacture of special
                 equipment that is not yet available in the market (this includes s-CO 2  heat exchangers and
                 turbine). A complete set of technical documents concerning power cycles and equipment
                 for s-CO 2 , as well as the main problems associated with this working fluid (i.e., corrosion
                 and erosion in the associated equipment) are available at: http://energy.sandia.gov/en-
                 ergy/renewable-energy/supercritical-co2.
                   Another interesting research topic related to central receiver technology is the use
                 of air, either at atmospheric pressure or under pressure. As air is freely available, the
                 development of a central receiver technology using air as working fluid is a very compel-
                 ling option. Central receivers using air at atmospheric pressure are made of ceramic or
                 metallic porous elements that heat the air flow circulating through them. The ceramic or
                 metallic porous elements composing the receivers are heated by the concentrated solar
                 radiation reflected by the heliostats, and the heat is then transferred to the air. The hot
                 air leaving the receiver is then sent to a thermal storage system and/or to a steam gen-
                 erator (air/water heat exchanger) where the superheated steam needed for the Rankine
                 cycle of the PCS is produced. The thermal storage vessel and medium suitable for this
                 type of central receiver system must withstand high-temperatures (>800°C) and heavy
                 thermal cycling without degradation. So far, pellets of alumina (Al 2 O 3 ) have been often
                 used as high-temperature storage medium in experimental facilities. Fig. 7.11 shows the
                 scheme of the pilot plant installed at the Plataforma Solar de Almería research facility
                 (PSA, www.psa.es).
                   Central receiver plants using atmospheric air have a lower efficiency than those with
                 molten salt receivers (Fig. 7.8). However, the simplicity and ease of operation of volumetric
                 receivers with atmospheric air could compensate for their lower efficiency. It must be kept
                 in mind that overall plant efficiency is not the only key aspect of a CSTP plant, because
                 the investment and operation and maintenance costs also play a significant role in the
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