Page 220 - A Practical Introduction to Optical Mineralogy
P. 220

COLOUR OF MINERALS  IN  PPL

                   Cubic                                                                             5.1.4  Identification of minerals using reflectance measurements
                   Isometric
                                                                                                     Accurate spectral reflectance curves are now available for all the com-
                                                                                                     mon  ore minerals.  An  identification  scheme described by  Bowie  and
                                                                                                     Simpson  (1980)  is  based  on  reflectance  values  at  the  four  standard
                                            cube  100        dodecahedron 110                        wavelengths 4  70, 546, 589 and 650 nm. Having measured several grains
                                                                                                     of the unknown mineral at the four standard wavelengths, the results are
                   Uniaxial                                                                          compared  with  the  reference  values  on  linear  charts.  If  certain
                                                                                                     identification  cannot  be  achieved  immediately,  then  microhardness
                   Hexagonal                 m                                                       measurements or qualitative properties may be used to supplement the
                                             w
                                            prism  IOiO  •            .   .   .  '                   quantitative  measurements.  An  advantage  of  their  method  is  that
                                                                                                     although sophisticated research microscopes are required for accurate
                                            basal pinacoid 0001   rhombohedron  lOll                 determination of spectral reflectance curves, relatively simple apparatus
                                                                                                     can be used to provide satisfactory reflectance values at the four stan-
                   Tetragonal                                                                        dard wavelengths.
                           A                                    6                                    5.2  Colour of minerals in PPL




                           v.PY"mid Ill                              .
                                            basal pinacoid 001   dipyramid  101                      Recognition  of the colour of minerals  in  polished  section  is  useful  in
                                            prism  110        pnsm  100                              their  identification,  but unfortunately  most  minerals  are only slightly
                                                                                                     coloured and the actual colours seen are easily changed. Colour change
                   Low symmetry                                                                      may be real, for example it may result from slight tarnishing; or it maybe
                   Triclinic                                                                         illusory, for example it may be caused by a varying background colour
                                               8J               OQ:J                                 to a better understanding of colour and its use in mineral identification.
                                                                 I~
                                                                                                     due to differing associated phases.
                                                                                                      The application of quantitative colour theory to ore minerals has led

                          pinacoids  Ill, IiI .  I i l.  IIi   basal pinac()id 001   basal pinacoid 001   The colour perceived by the observer depends on the nature of the light
                                                                                                     source,  the  spectral  reflectance  curve  of  the  mineral  and  how  the
                                              pinacoids  110,  110   pinacoids 010,  100
                                                                                                     observer interprets the spectral distribution of the light reaching his eye
                   Monoclinic                                                                        in  terms of the mineral's surroundings. There is  also the possibility of
                                                                                                     slight  imperfection  in  the observer's colour vision. Obviously  anyone
                                 '
                                 .                                                                   who is  severely colour blind is  going to have great difficulties  in  using
                              00                                                                     reflected light  microscopy.
                                                                                                      The quantitative colour system used is that of the Commission Inter-
                          basal pinacoid 001                    pinacoid  101                        nationale d'Eclairage 1931 (Judd 1952). If the standard data and their
                          front pinacoid  I 00   basal pinacoid 00 I   pinacoid  I Oi
                          side pinacoid 010   prism  110        side pinacoid 010                    theoretical treatment are accepted, the only measurement required to
                                                                                                     obtain quantitative colour values of a polished section of a mineral is its
                             ·                                                                       spectral reflective curve. This curve represents the modification made by
                               .
                               ·
                               ·.
                                .
                                "
                             "
                   Oclhochombi< ~.                                                                   the  polished  surface  of the  mineral  to  the  white  colour  of  the  light
                              .·
                               .
                              ·
                                 ·
                                ..
                                 ··
                                 ..
                                '
                                .·.·
                              ·
                               Ill
                             .··
                                 0
                                                                                                     source. A surface with 100% reflectance at all visible wavelengths would
                              •,
                                                                                                     obviously  appear  bright  white  (the  colour  of the  source  lamp).  All
                                                               basal pinacoid 001                    minerals have reflectances much less than  100%, and since R % varies
                                            basal  pinacoid 001
                           dipyramid  Ill   prism  110         front pinacoid  I 00                  with wavelength this leads, but not in a simple way, to colour. Using the
                                                               side pinacoid 010
                                                                                                     CIE (1931) colour diagram (described in detail in Section 5.2.1), miner-
                   Figure 5.4  Crystal symmetry.                                                     als can be plotted and their colours compared quantitatively as well as
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