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66     CHAPTER 4 AVAILABILITY AND EXERGY




             through a reversible heat engine, as shown in Fig. 4.2(b). In the latter case, useful work would have
             been obtained, and this would be equal to

                                               dw R ¼ h dQ;
                                                        R
             where h R is the thermal efficiency of a reversible heat engine operating between T and T 0 , and dQ is
             the heat transfer to the system,

                                                    T   T 0
                                                ¼        dQ:
                                                      T
                Hence, the work output obtainable from this reversible heat engine as the system changes state
             from 1 to a is

                                            Z a            Z a
                                              T   T 0        T   T 0
                                     w R ¼          dQ ¼           c p dT
                                                T               T
                                            1              1

                                                             T a
                                       ¼ c p ðT a   T 1 Þ  T 0 ln
                                                             T 1
                                                                       365:7

                                        ¼ 1:005   ð365:7   550Þ  300 ln       ¼ 62:18 kJ=kg
                                                                        550
                Now consider process a to 2.
                First, evaluate the specific volume at 2, v 2 .
                                           p 1 T 2  2   300
                                      v 2 ¼    v 1 ¼      v 1 ¼ 1:0909v 1
                                           p 2 T 1  1   550
                                                                       k
                The expansion from a to 2 is isentropic and hence obeys the law pv ¼ constant. Thus the system
             work is

                                   ð1   1:0909   2   0:6649Þ  0:7896   10 5

                         w sys    ¼                                   ¼ 47:16 kJ=kg
                             a 2           1   1:4             10 3
                                   Z 2
                                           1   10 5
                         w surr j a 2  ¼  p 0 dv ¼  3  ð1:0909   0:6649Þ  0:7896 ¼ 33:63 kJ=kg
                                             10
                                   a

                         w usej a 2  ¼ w sys   a 2    w surr j a 2  ¼ 13:52 kJ=kg
                The energy available to drive a reversible heat engine is zero for this process because it is adiabatic;
             hence

                                                 w R j a 2  ¼ 0:
                The work terms for the total process from 1 to 2 can be calculated by adding the terms for the two
             subprocesses. This enables the solutions to questions (v) to (viii) to be obtained.
                The gross work done by the system is


                        w gross ¼  X  w sys þ w R ¼ 52:96 þ 47:16 þ 62:18 þ 0 ¼ 56:38 kJ=kg
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