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14.4 3D PRINTING OF PERSONALIZED SILICONE IMPLANT                 283








                                                            Shear thinning

                                                             Yield stress
                                                            Thixotropy


                                              (A)
                                                                 Newtonian
                                                                shear thickening  Shear thinning
                             Viscocity







                                                                                      Lower shear
                                                                      High shear
                                                                      stress risk     stress
                                                   Shear rate
                            (B)                                 (C)
                                                                High yield stress  Low yield stress  Adapted yield
                                                                                         stress
                             Shear rate








                                        Yield stress  Stress
                            (D)                                (E)  Shear thinning and thoxtopic time are supposed adapted
                                                                 High thixotropic  Low thixotropic
                                                                    time              time



                             Storage modulus








                              Thixotropic              Time
                            (F)  time                         (G)  Shear thinning and yield stress are supposed adapted
           FIG. 14.10  (A) Rheological properties of interest and localization. (B) Shear thinning behavior. (C) Consequence of shear thinning behavior on
           3-D printing. (D) Yield stress behavior. (E) Consequence of yield stress behavior on 3-D printing. (F) Thixotropic behavior. (G) Consequence of thixo-
           tropic behavior on 3-D printing. Graphics were kindly provided by 3dFAB, University Lyon 1.

              Thixotropy is a time-dependent shear thinning property. It can be used to describe the restructuration time of mate-
           rial after a destructuration step. In 3-D printing, the destructuration occurs when the material flows through nozzle
           and the restructuration begins just after material extrusion. If the used material presents a high thixotropy (long thix-
           otropy time), the recovering of the rheological properties will be slow, and the shape of the printed layer will not be
           maintained when the next layer will be deposited. The thixotropic behavior can be measured with two-step transient
           tests: stress growth in flow mode and time sweep test in oscillatory mode.


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