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07_Chap_Wang.qxd  05/05/2004  4:19 pm  Page 331
                    Flare Process                                                             331

                    the recent regulatory requirements of 98% destruction efficiency for flares. The calcu-
                    lation procedure will be illustrated for emission stream 3 described in Table 1 using a
                    steam-assisted flare system. Note that flares often serve more than one process unit
                    and the total flow rate to the flare needs to be determined before the following calcu-
                    lation procedure can be applied. A number of flare sizing software packages have
                    been developed. One example is the Pegasus algorithm, described elsewhere (8). Related
                    hazardous-waste-treatment technologies and HAP emission control technologies can
                    be found from two United Nations Industrial Development Organization (UNIDO)
                    technical reports (12,13).


                    2. PRETREATMENT AND ENGINEERING CONSIDERATIONS
                    2.1. Supplementary Fuel Requirements
                       Based on studies conducted by the EPA, relief gases having heating values less than
                    300 Btu/scf are not ensured of achieving 98% destruction efficiency when they are
                    flared in steam-assisted or air-assisted flares. Therefore, the first step in the evaluation
                    procedure is to check the heat content of the emission stream and determine if additional
                    fuel is needed (1–3).
                       In a permit review case, if the heating value of the emission stream is less than 300
                    Btu/scf and no supplementary fuel has been added, the application is considered
                    unacceptable. The reviewer may then wish to follow the following calculations. If the
                    reported value for the emission stream heat content is above 300 Btu/scf, the reviewer
                    should skip to Section 2.3.
                       If the emission stream heating value is less than the 300 Btu/scf required to achieve
                    a destruction level of 98%, it is assumed that natural gas will be added to the emission
                    stream to bring its heat content to 300 Btu/scf. Calculate the required natural gas
                    requirements using
                                               Q = ( [  300 − ) ]  582                         (1)
                                                            hQ
                                                                e
                                                             e
                                                 f
                    where Q is the emission stream flow rate (scfm), Q is the natural gas flow rate (scfm),
                            e                                     f
                    h is the emission stream heating content or value (Btu/scf), and 582 = 882−300; 882 is
                     e
                    the lower heating content or value of natural gas (Btu/scf). If the emission stream heating
                    value is greater than or equal to 300 Btu/scf, then Q = 0.
                                                                  f
                    2.2. Flare Gas Flow Rate and Heat Content
                       The flare gas flow rate is determined from the flow rates of the emission stream and
                    natural gas using
                                                     Q   = Q + Q                               (2)
                                                      flg   e   f
                    where Q   is the flare gas flow rate (scfm). Note that if Q = 0, then Q  = Q .
                            flg                                        f           flg  e
                       The heating value of the flare gas (h ) is dependent on whether supplementary fuel
                                                       flg
                    is added to the emission stream. When h is greater than or equal to 300 Btu/scf, then
                                                         e
                    h   = h . If h is less than 300 Btu/scf, supplementary fuel is added to increase h to 300
                     flg  e    e                                                          e
                    Btu/scf, and h  = 300 Btu/scf.
                                 flg
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