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Heat and mass transfers in the context of energy geostructures  95


                      fine-grained soils (Rees et al., 2000). In view of this latter evidence, radiation is
                      usually neglected in the analysis of heat transfer characterising geomaterials.
                   • The contribution of radiation can be considered negligible with respect of that of
                      convection for the heat carrier fluid flowing in the pipes.



                   3.7 Energy conservation equation
                   3.7.1 General

                   The energy conservation equation expresses the principle of conservation of energy.
                   This governing equation is also often termed the energy equation.


                   3.7.2 Fourier heat conduction equation

                   The equation that governs the conservation of energy in the context of the analysis of
                   heat transfer only characterised by conduction is typically termed Fourier heat conduc-
                   tion equation. This equation can be derived by considering Fourier’s law of heat con-
                   duction expressed in Eq. (3.2) for a representative volume subjected to arbitrary
                   thermal conditions on its surfaces with internal volumetric heat generation _q per unit
                                                                                      v
                   time and neglecting any conversion of mechanical energy into heat (cf. Fig. 3.11).
                   The energy balance for the elementary volume reads


                      Rate of heat entering through       Rate of heat         Rate of energy
                                                  1                       5
                    the bounding surfaces of a volume  generation in a volume  storage in a volume
                      Accordingly, the generalised Fourier heat conduction equation reads

                                                                 @T
                                                 ð                                       ð3:14Þ
                                              r  λrTÞ 1 _q 5 ρc p
                                                          v
                                                                 @t
                   where ρ and c p are the density and the specific heat of the considered medium, respec-
                   tively, and t is the time. The term on the right-hand side of the equation represents
                   the variation of internal energy in the medium over time.


                                                           dx
                                                  dz
                             y
                                                                  dy
                                                                      –     ∂
                                         –λ ∂T                         λ ∂T +  λ ∂T  dx dydz
                                             dydz
                                           ∂x                           ∂x ∂x  ∂x
                                       x
                           z
                   Figure 3.11 Balance of variables over the representative volume.
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