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Heat and mass transfers in the context of energy geostructures  97


                   where α d is the thermal diffusivity of the medium given by
                                                           λ
                                                     α d 5  ρc p                         ð3:20Þ


                   where ρc p is the volumetric heat capacity. The thermal diffusivity measures the ability
                   of a material to conduct thermal energy relative to its ability to store thermal energy
                   (Hermansson et al., 2009). Materials of large α d will respond quickly to variations in
                   their thermal environment, while materials of small α d will respond more slowly. The
                   thermal diffusivity of a medium is indicative of the propagation speed of the heat into
                   the body during temperature variations. The higher the value of α d is, the faster prop-
                   agation of heat within the medium is.


                   3.7.4 Laplace’s equation
                   The particular case in which the temperature distribution is independent of time and
                   no heat sources are present can be of interest, and involves the Laplace’s equation (e.g.
                   for the temperature field)
                                                      2
                                                     r T 5 0                             ð3:21Þ
                      Eq. (3.21) is associated with steady-state conditions and often represents the basis
                   for analysis and design considerations.


                   3.7.5 Energy conservation equation
                   When convection and conduction characterise the heat transfer, the energy conserva-
                   tion equation reads

                                           2           @T
                                                                                         ð3:22Þ
                                                           1 ρ c p;f v rf ;i  rT
                                        λr T 1 _q 5 ρc p
                                                              f
                                                 v
                                                        @t
                   where v rf ;i is the fluid velocity vector.
                      The expression of the energy conservation reported in Eq. (3.22) presents two
                   unknowns: the temperature field, T, and the displacement field of the moving fluid,
                   u f ;i (included in the term v rf ;i 5 @u f ;i =@t). Therefore the only Eq. (3.22) makes the
                   solution   of   conduction convection    related   problems    undetermined.
                   Conduction convection heat transfer problems can be addressed by solving Eq. (3.22)
                   and the mass conservation equation, under the assumption of negligible influences of
                   the phenomena involved in the equilibrium of the moving fluid (i.e. incompressible
                   inviscid flow). The previous aspect explicates the essence of the thermohydraulic cou-
                   pling between heat transfer and mass transfer that takes place as soon as convection is
                   considered.
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