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98    Analysis and Design of Energy Geostructures


                3.7.6 Typical values of volumetric heat capacity
                Typical values of volumetric heat capacity for different materials involved in energy
                geostructures applications are provided in Table 3.9. Distinct values of specific heat
                and bulk density are reported in Table 3.10. The typical evolution of volumetric heat
                capacity with water content for soils (e.g. unfrozen) is presented in Fig. 3.13.
                   The estimation of the volumetric heat capacity of materials is usually simpler than
                that of the thermal conductivity. In such cases, in contrast to the estimation of the
                effective thermal conductivity, a linear function of the capacities and volume ratios of
                the phases characterising the material is sufficient to have a representative estimate of



                     Table 3.9 Volumetric heat capacity of materials characterising energy geostructures.
                     Material                             Volumetric heat capacity,
                                                              ρc p [MJ/(m 3   C)]
                                                 Dry                 Saturated

                     Clay                        1.5 1.6             1.6 3.4
                     Silt                        1.5 1.6             1.6 3.4
                     Sand                        1.3 1.6             2.2 2.9
                     Gravel                      1.4 1.6             2.4

                     Peat                                        0.5 3.8
                     Claystone/Siltstone                         2.1 2.4
                     Sandstone                                   1.6 2.8
                     Quartzite                                   2.1 2.2
                     Marl                                        2.2 2.3
                     Limestone                                   2.1 2.4
                     Argillaceous schists                        2.2 2.5
                     Micaschists                                   2.2
                     Metaquartzite                                 2.1
                     Marble                                        2.0
                     Gneiss                                      1.8 2.4
                     Rhyolithe                                     2.1
                     Peridotite                                    2.7
                     Granite                                     2.1 3.0
                     Gabbro                                        2.6
                     Diorite                                       2.9
                     Basalt                                      2.3 2.6
                     Concrete                                    1.8 2.0
                     Steel                                        3.12
                     Water                                        4.186
                     Air                                         0.0012
                     Source: Data from Pahud, D., 2002. Geothermal Energy and Heat Storage. Laboratorio di Energia,
                     Ecologia ed Economia, Canobbio.
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