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CHAP TER 1 8. 2       Materials for consideration and use in automotive body structures


                Table 18.2-9 HSS strengthening mechanisms. (Illustrations courtesy of Thyssen Krupp Stahl.)
                Rephosphorized steel is an example of a substitutional
                type where the larger atom is straining the lattice while  Solid-solution  Substitutional  Matrix atom
                                                                      formation  atom
                smaller carbon, oxygen and nitrogen atoms occupy the                                  Interstitial atom
                interstices between the iron atoms
                                                                      Bake-hardening  Interstitial    Edge dislocation
                                                                      effect     atom


                Interstitial-free ‘IF’ steels are vacuum degassed to remove  2.5
                the carbon and oxygen atoms which impede the
                movement of dislocations and therefore increase the ease             IF
                of deformation (positive effect on forming, negative effect          steel IF
                on dent resistance). IF high strength steels therefore     value 2.0    HSS  Future
                                                                                            development
                combine the increased ductility associated with the ferritic  r   Rephos-
                                                                           1.5    phorized
                matrix but gain enhanced strength from substitutional
                                                                                  steel
                phosphorus, silicon and manganese additions.                             Precipi-
                                                                                         tation  Dual phase
                  Bake-hardening steels derive their increase in                         hardened
                                                                           1.0           steel  steel
                strength from a strain ageing process that takes place on

                paint baking at circa 180 C. Sufficient carbon is retained    0 10  20  30 40  50 60 70  80 90 100
                                                                                                    2
                in solution during either batch or continuous annealing to           Tensile strength (kgf/mm )
                                                                             Relationship between r value and tensile strength
                allow migration to dislocations following cold deformation.
                These are effectively locked, requiring a higher
                subsequent stress to recommence deformation, thereby
                increasing dent resistance.
                  The strength of both rephosphorized and IF high
                strength steels can be enhanced by this mechanism but
                different modes of carbon retention are required to                 B
                prevent premature diffusion of carbon at either room                        Bake hardening
                temperature in storage, or during the application of zinc by
                hot dipping. In continuous processing this can be achieved                  Strain hardening
                by incorporating an over ageing treatment and alloying       Stress  A
                whereby just enough carbon is retained in solution to
                allow the mechanism to occur at elevated temperatures.
                The degree of cold deformation will reduce the 6BH
                response correspondingly (see the diagram below).



                High strength low alloy steels gain their increased
                                                                       Grain     Coarse-
                strength from the fine grain structure (smaller than ASTM  boundaries  grained       Fine-grained
                No. 10) and fine dispersion of precipitates (e.g. niobium
                and titanium carbo-nitrides) both of which impede                Coarsely
                dislocation movement thereby increasing the flow stress.  Precipitations  dispersed  Finely dispersed



                Multiphase steels derive their strength from thermo-
                mechanical processing, i.e. carefully balanced rolling,              Si, P, Al
                                                                               Ac 3  Al,P
                coiling and compositional control within the boundaries                    Ferrite
                shown in the diagram opposite. Types of steel included in                C, Mn, Cr, B
                                                                                           Si, P
                this category are dual phase, TRIP/TWIP, complex phase        Temperature  Ac 1 Al,P  pearllte C, Mn, Cr, Mo, Al
                and martensitic phase as described below.                            Al      bainite C, Mn, Cr, Mo
                                                                               Ms C, Mn
                                                                                    DP – steel  TRIP – steel
                                                                                           Time
                                                                          Influence of alloying elements on transformation behaviour







                    650
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