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Indicators for sustainability assessment  93


              10 Pretreatment of bagasse

              The pretreatment step comprehends drying, roasting, and crushing, and pre-
              pares biomass for the fluidized bed gasification process, providing adequate
              granulometry and humidity, and improving energy density.



              11 Production and cleaning of syngas

              Production and cleaning of syngas encompasses the gasification steps in flu-
              idized bed and cleaning of the obtained gas. Gasification is a complex pro-
              cess, sensitive to several factors such as gasification temperature, equivalence
              ratio, biomass granulometry, and demands oxygen with elevated purity.
                 Therefore the production step of syngas includes a unit for air separation,
              which produces the oxidizing agent for gasification. The quality of syngas
              limits its utilization in other processes, and therefore cleaning has the objec-
              tive of removing unwanted compounds, enabling its utilization in BIG-
              GTCC cycles and in FT synthesis.
                 Fig. 4.13 presents the mass balance of the syngas production step. It con-
              siders the energy flows associated with the processing of 1 tonne of sugarcane
              for the Base Case (BSE), where 50% of syngas goes to the FT synthesis and
              50% to the BIG-GTCC.

                        Dryer  Electricity    Electricity   Electricity
                       agent in  26 kWh       4.9 kWh       41.16 kWh
                                                                      Pretreatment
                Bagasse            Bagaço               Bagasse
               50% moisture  Dry  15% moisture  Torrefaction  torrefeid  Grind
                 1000 kg            588 kg              411.6 kg

                                              Torgas     Torrefied bagasse
                                              176.4 kg
                   Dryer agente out  Water              granulometry 0.1 mm
                                412 kg                      411.6 kg
                                                Syngas
                                               production
                                                                 Electricity
                                                                 12.8 kWh
                             Electricity  ASU  O 2  Gasification
                             86.4 kWh      288.1 kg
                                                                Ash
                                                                14.4 kg
                                                      Syngas
                                    Electricity       685.3 kg
                                    2.54 kWh
                                                   Rectisol
                                                                Acid gases
                             Steam (4.8 bar, 180°C)             (CO 2  e H 2 S)
                                 33.6 kg                         211.4 kg
                                                  Clean syngas
                                                    473.9 kg
              Fig. 4.13 Mass and energy balances for the production and cleaning of syngas.
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