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88    Biofuels for a More Sustainable Future


          • Cases FT (Fischer-Tropsch): Considers the thermochemical route and the
            utilization of all the available bagasse available at the syngas production
            plant for Fischer-Tropsch synthesis. This process is characterized by the
            high demand of energy in the processes that constitute the plant. It was
            considered that a BIG-GTCC cycle would meet part of this demand,
            using 20% of the syngas produced.
          • Case BGT (BIG-GTCC): Considers the thermochemical route for the
            production of electricity, using all the available bagasse in the gasification
            process. Therefore the produced syngas will be used as fuel for a gas tur-
            bine within a BIG-GTCC cycle, and does not require adjustments in its
            composition, as occurred indifferently from the FT case.
          Each case assumes a sugar and ethanol industry that is energetically self-
          sufficient, with electric mills. The self-produced electricity operates equip-
          ment such as pumps, agitators, transporters, and lighting.
             After the syrup extraction process, bagasse is obtained with a 50% humid-
          ity content. For each tonne of sugarcane processed, 280kg on humid basis is
          obtained, which corresponds to the available bagasse (Marino, 2014;
          Oliv erio, 2014; Hassunai et al., 2005). Straw represents 14% of the sugarcane
          available in the field (Marino, 2014; Oliv erio, 2014; Hassunai et al., 2005),
          and therefore for each tonne of sugarcane cropped, there is 140kg straw
          left in the field. Assuming a plant with a processing capacity of 1200tonnes
          of sugarcane per hour, this value corresponds to 86% of the sugarcane avail-
          able in the fields, and the remaining 14% refer to straw (equivalent to
          195.35tonnes/h).
             It is recommended that the maximum amount of straw removed from
          the field is 50%, as half of the straw should be left on the soil to reduce ero-
          sion, allow the recirculation of nutrients and maintain the humidity levels of
          the soil (Marino, 2014; Hassunai et al., 2005). The amount of available straw
          (humidity content 15%) for utilization corresponds to 97.68t/h, and herein
          the rounded value of 97.60t/h will be considered. Regarding bagasse, part
          is mixed with straw and used as fuel for the steam boiler, in a 50%–50%
          proportion, as suggested by the manufacturer CALDEMA (Marino,
          2014). It is also recommended that a 10% share of the bagasse generated after
          syrup extraction is stored (CGEE, 2010), which corresponds to 33.6t/h.
             After this separation, there is 204.8t/h of bagasse that can be utilized as a
          resource in the biorefinery processes, which contemplates biochemical and
          thermochemical conversion routes.
             Fig.4.9presentsthegeneralschemeofthebiorefinery,inwhichtheafore-
          mentioned processes are integrated within an existing plant. Table 4.2 pre-
          sents the operational parameters adopted for the simulation, common to all
          study cases. LHV refers to the lower heating value.
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