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146                                                                               Boiler Operator’s Handbook

               tioned  first?  Simply  because  paper  properties  change  paratus) in a cabinet immediately inside the door. Do
               with temperature and moisture content and keeping it  not fail to read the instructions and, preferably, try out
               consistently spaced between printing rolls containing  the apparatus so you know how to operate and use it.
               different colors of ink, a process called registration, re-  Encourage other operators to do the same because they
               quired maintaining the temperature and humidity in  may have to use it to reach you and carry you out of the
               the plant.                                           space in the event of an incident.
                    Many other fluids can be used as refrigerants but     Figure 5-1 is a tabulation of our more common re-
               they have undesirable properties. Some known to cause  frigerants including replacements for refrigerants that
               cancer were used in early systems and others, such as  are no longer allowed to be used in new equipment. You
               propane,  are  not  used  because  they’re  flammable  or  will note that there are color codes for most refrigerants.
               heavier than air. Along with water another natural sub-  Containers of the refrigerant are painted that color in an
               stance used as a refrigerant is ammonia. It’s an excellent  effort to ensure a system is not charged with the wrong
               refrigerant but it’s also flammable, corrosive, and poi-  refrigerant or refrigerants are not mixed. Most refriger-
               sonous. If it leaks from the refrigeration system it can  ant systems will fail to operate properly when exposed
               catch  on  fire,  ruin  materials  stored  in  the  refrigerated  to a mixed refrigerant. There are, however some refrig-
               spaces and kill people. That’s why it’s only used in facil-  erants which are intentional mixtures; these are known
               ities that aren’t normally open to the public and moni-  as binary refrigerants, a mix of two.
               tored constantly for leaks.                              The question mark for replacement of R-22 is there
                    Then, in the later half of the 20th century we dis-  because; at the time of writing this there was no con-
               covered that Freon (a trade name of the DuPont Com-  sensus on a suitable replacement for it. Unlike the CFC
               pany that became more or less a generic label for refrig-  refrigerants which can not be made anymore the HCFC
               erants) was not as safe as we thought. It wasn’t flam-  R-22 is scheduled to be replaced and no longer manufac-
               mable nor poisonous and it was lighter than air so it  tured sometime between now and the year 2030. R-134a
               wouldn’t pool inside a basement like propane does but,  has become the standard for all applications that used to
               being lighter than air it rose up in the atmosphere until  use R-12. The orange containers of R-11 and containers
               it got to the stratosphere then disassociated releasing  of R-123 are actually  drums  because they  are a  liquid
               chlorine atoms that break down ozone. Located about  at normal atmospheric conditions; in use the evaporator
               30 miles above the surface of the earth the stratosphere  for those refrigerants operates in a vacuum.
               contains an ozone layer that works like a filter to screen     R-404a is one of the binary refrigerants which have a
               out harmful ultraviolet radiation from the sun. By the  range of saturation temperatures between two conditions
               time the chemistry of the action of most refrigerants  known as dew point and bubble point. Because it’s a mix-
               (CFCs, short for chlorofluorocarbons) on the ozone lay-  ture of two refrigerants with different saturation condi-
               er was recognized the ozone deple-
               tion was so extensive that there was
               a “hole” in the ozone layer over the
               North  Pole.  International  efforts  to
               limit the release of refrigerants and
               development of new refrigerants
               that lack chlorine have reduced the
               damage to the ozone layer and it is
               now recovering.
                    Part of the solution is heavier
               than air refrigerants that will not
               reach the upper atmosphere. How-
               ever, they can accumulate in spaces
               containing the refrigeration equip-
               ment with the potential of suffocat-
               ing people. Should you happen to
               go to work in a plant that uses one
               of those refrigerants you should find
               a SCBA (self contained breathing ap-         Figure 5-1. Information on some common refrigerants
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