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Introduction to Polymers                                                      15



                 TABLE 1.10
                 U. S. Chemical Trade—Imports and Exports (Millions of Dollars)
                 Year ➔                       1985                1994                2008
                                        Imports   Exports   Imports   Exports   Imports   Exports
                 Organic chemicals       6,000     4,600    12,800    10,800     34,800    47,700
                 Inorganic chemicals     2,000     2,000     4,100     4,100     13,100    16,800
                 Oils and perfumes        —         —        3,500     2,000     12,100     9,600
                 Dyes, colorants          —         —        2,300     1,900      6,400     3,100
                 Medicinals/pharmaceuticals  2,700  1,080    6,100     4,700      38,200    59,600
                 Fertilizers             2,160     1,000     2,700     1,300      7,500     8,400
                 Plastics and resins     3,800     1,600     8,500     3,300      40,100 *  18,800 *
                 Others                  5,300     4,220     7,600     2,700      26,000    12,700
                 Total chemicals †      22,000     14,500   51,600    33,400     179,100   176,800
                 Total                  213,000   345,000   502,800   669,100   1,855,000  1,954,000

                 * Includes both plastics in primary and nonprimary forms but does not include rubber and rubber products.
                 † Includes nonlisted chemicals.
                 Source: Department of Commerce.



                 polymeric or contain a large amount of polymeric materials. Table 1.9 lists some general groupings
                 of important polymers. Welcome to the wonderful world of polymer science.
                    The number of professional chemists directly employed with polymers as part of their interest and
                 assignment is estimated to be 40%–60% of all chemists. As the diversity of chemistry increases,
                 the dispersion of those dealing with polymers increases. Polymer chemistry is a major tool applied
                 in biomedical research, synthesis, manufacturing, chemical engineering, pharmaceutical efforts, the
                 environment, communications, and so forth. “As it was in the beginning” polymers continue to draw
                 strength from those with diverse training, allowing polymers to directly contribute to solutions for most
                 of our technological problems including fuel and transportation, building and construction, commu-
                 nication, medicine and dentistry, and so on. Analytical chemistry is related to the analysis of materi-
                 als; inorganic is related to the catalysts employed in the synthesis of natural and synthetic polymers;
                 organic is related to the synthesis of diverse materials; physical chemistry describes the kinetics, ther-
                 modynamics, and properties of macromolecules; and biological chemistry deals with biopolymers.
                    Polymeric materials, along with several other chemical industrial products, contribute positively
                 to the balance of trade (Table 1.10). In fact, plastics and resins show the greatest value increase of
                 exports minus imports with more than $20 billion net favoring exports. The polymer-intense mate-
                 rial numbers are higher than that noted in Table 1.10 since fi ber and rubber materials are absent as
                 a separate entry. Even so, the fi gures demonstrate the positive nature polymers play in our balance
                 of trade situation.
                    Table 1.11 contains a listing of the major chemical producers in the United States and the world.
                 These producers are involved directly and/or indirectly with some form of synthetic polymers.
                 Essentially, all of the industrially advanced countries of the world have major chemical producers.
                 Table 1.11 contains a partial listing of these companies.
                    Thus, polymers play a critical role in our everyday lives, actually forming the basis for both plant
                 and animal life, and represent an area where chemists continue to make important contributions.

                 1.4   ENVIRONMENTAL ASSESSMENT

                 Daily, we are becoming more aware of the importance of environmental planning and good environ-
                 mental actions (practices) and their effect on us. This emphasis is being driven by a number of pressures,







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