Page 123 - Chemical equilibria Volume 4
P. 123

and:
                                             ⎛    β + u 2∑ β ⎞       Molecular Chemical Equilibria     99
                                               −
                                 x  32u = ⎜  −  2  y ⎜  1 2  1  i  ⎟  ⎟                  [3.96]
                                             ⎝         β 3   ⎠
                             At the intersection of the two lines, the values of the x and y coordinates
                           are the same, which, if we subtract the two equations [3.95] and [3.96], term
                           by term, leads us to:

                                               ∑  β
                                  ( 2 u − u 1 ) 2y=  I  i  (u − u 1 )                    [3.97]
                                    2
                                                      2
                                                β
                                                  3
                             This gives us the coordinates of the intersection:
                                      β
                                 y =   3                                                [3.98a]
                                     ∑  β i
                                  I

                           and:
                                     β − 2β
                                 x =  3     1                                           [3.98b]
                                  I
                                       3 ∑ β i


                                                            A 3






                                                            E

                                                        M
                                                                          A 1
                                             A 2
                                                       O
                                        Figure 3.16. Plot of the iso-composition line and the
                                                  equilibrium point [SOU 68]



                             This intersection does not depend on the values of u 1 and u 2, meaning that
                           the point of intersection O, defined above and whose coordinates are given
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