Page 308 - Elements of Chemical Reaction Engineering 3rd Edition

280 Collection and Analysis of Rate Data Chap. 5

P5C-6 The selective oxidation of toluene and methanol over vanadium pentoxide-sup-
ported alkali metal sulfate catalysts was studied recently [AIChE J., 27(1), 41
(1 98l)l. Examine the experimental technique used (equipment, variables, etc.)
in light of the mechanism proposed. Comment on the shortcomings of the anal-
ysis and compare with another study of this system presented in AZChE J.,
28(5), 855 (1982).

CD - ROM MATERIAL

Learning Resources
1. Summary Notes for Lectures 9 and 10
3, Interactive Computer Modules
A. Ecology
4. Solved Problems
A. CDP5-B, Oxygenating Blood
B. Example CD5-1 Integral Method of Analysis of Pressure-Time Data
e Living Example Problems
1. Example 5-6 Hydrogenation of Ethylene to Ethane
e Professional Reference Shelf
1. Weighted kast Squares Analysis
2. Experimental Planning
3. Evaluation of Laboratory Reactors
e FAQ [Frequently Asked Questions]- In UpdatesFAQ icon section
e Additional Homework Problems

CDP5-AB The reaction of penicillin G with ",OH is carried out in a batch
reactor. A colorimeter was used to measure the absorbency as a func-
tion of time. [lst Ed. P5-iOJ
CDP5-BB The kinetics of the deoxygenating of hemoglobin in the blood was
studied with the aid of a tubular reactor. [lst Ed. P5-31
CDP5-Cc The kinetics of the formation of an important propellant ingredient,
triaminoguanedine, were studied in a batch reactor where the ammo-
nia concentration was measured as a function of time. [2nd Ed. P5-61
cDPs-DB The half-life of one of the pollutants, NO, in autoexhaust is required.
[lst Ed. P5-111
CDP5-EB The kinetics of a gas-phase reaction A2 + 2A were studied in a con-
stant-pressure batch reactor in which the volume was measured as a
function of time. [lst Ed. P5-61

SUPPLEMENTARY READING

1. A widevariety of techniques for measuring the concentrations of the reacting spe-
cies may be found in

ROBINSON, J. W., Undergraduate Instrumental Analysis, 5th ed. New Yorki
Marcel Dekker, 1995.
SKOOG, D. A., Principles of Instrumental Analysis, 3rd ed. Philadelphia: Holt,
Rinehart and Winston, 1985.