Page 30 - Elements of Chemical Reaction Engineering Ebook
P. 30

Mole Balances                           1


















                                                 The first step to knowledge
                                                 is to know that we are ignorant.
                                                                            Socrates (470-399 B.c.)

                              Chemical kinetics  and reactor  design are at the heart of  producing almost id1
                              industrial chemicals. It is primarily a knowledge of  chemical kinetics and reac-
                              tor  design that distinguishes the chemical engineer from other engineers. %he
                              selection  of  a  reaction  system  that  operates  in  the  safest  and  most  efficient
                              manner can be the key to the economic success or failure of  a chemical plant.
                              For  example,  if  a  reaction  system  produced  a  large  amount  of  undesirable
                              product,  subsequent purification  and  separation of  the  desired product  could
                              make the entire process economically unfeasible. The chemical kinetic princi-
                              ples leanied here, in addition to the production of chemicals, can be applied in
                              areas  such  as  living  systems,  waste  treatment,  and  air  and  water  pollutioln.
                              Some of the examples and problems used to illustrate the principles of chemi-
                              cal  reaction  engineering  are:  the use  of  wetlands  to  remove toxic  chemicals
                              from rivers, increasing the octane number of  gasoline, the production of  anti-
                              freeze starting from ethane, the manufacture of computer chips, and the appli-
                              cation of  enzyme kinetics to improve an artificiaI kidney.
                                   This book fcicuses on a variety of  chemical reaction engineering topics.
                              It is concerned with the rate  at which chemical reactions take place, together
                              with  the mechanism  and rate-limiting  steps that control the reaction process.
                              The  sizing of  chemical  reactors  to  achieve production  goals is  an  important
                              segment.  How  materials  behave  within  reactors,  both  chemically  and  physi-
                              cally, is significant to the designer of  a chemical process,  as is how  the data
                              from chemical reactors should be recorded, processed, and interpreted.
                                   Before  entering  into  discussions  of  the  conditions  that  affect chemical
                              reaction  rates  and  reactor  design,  it  is  necessary  to  account  for  the  varioius
                              chemical species entering and leaving a reaction system. This accounting pno-
                              cess  is  achieved  through  overall  mole  balances  on  individual  species  in  the
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