Page 53 - Elements of Chemical Reaction Engineering Ebook
P. 53

~


                          24                                             Mole Balances   Chap. 1

                            before the stream is recycled include Synoil (a synthetic crude), water, methyl ethyl
                            ketone (MEK), alcohols, acids, and aldehydes. The reactor is operated at 25 atm and
                            350°C and at any one time contains  150 tons of catalyst. The catalyst feed rate is 6
                            to 9.5 tons/s,  and the gas recycle ratio is 2: 1.
                                 Packed Bed. The packed-bed reactor used at the Sasol plant to carry out Fis-
                            cher-Tropsch synthesis reaction is shown in Figure El-5.3. Synthesis gas is fed at a
                            rate of  30,000 m3/h (STP) at 240°C and 27 atm to the packed-bed reactor. The reac-
                            tor contains 2050 tubes,  each of  which  is 5.0 cm in  diameter and  12 m  in length.
                            The iron-based catalyst that fills these tubes usually  contains K,O  and SiO,  and has
         Use to produce wax   a specific area on the order of  200  m2/g. The reaction  products are light  hydrocar-
             for candles and   bons along with a wax that is used in candles and printing inks. Approximately 50%
              printing inks.   conversion of the reactant is achieved in the reactor.
                               s                                                      J




                              (     1-       Gas  inlet
                                             Steam heater
                    Steam
                   iniector                -Steam   outlet
















                                            bundle








                              Figure a-5.3  Packed-bed reactor. (Schematic and photpgraph dourtesy of
                              Sasol/Sastech W Limited.)

                              The aim of the preceding  discussion  on commercial  reactors is to give a
                         more detailed picture  of each of the major types of  industrial  reactors:  batch,
                         semibatch,  CSTR,  tubular,  fixed-bed  (packed-bed),  and  fluidized-bed.  Many
                         variations  and  modifications  of  these commercial  reactors  are in  current  use;
                         for  further  elaboration,  refer  to  the  detailed  discussion  of  industrial  reactors
                         given by Walas.

                          S.  M. Walas, Reaction  Kinetics for  Chemical Engineers  (New York:  McGraw-Hill,
                          1959), Chap.  1 1.
   48   49   50   51   52   53   54   55   56   57   58