Page 53 - Elements of Chemical Reaction Engineering Ebook
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24 Mole Balances Chap. 1
before the stream is recycled include Synoil (a synthetic crude), water, methyl ethyl
ketone (MEK), alcohols, acids, and aldehydes. The reactor is operated at 25 atm and
350°C and at any one time contains 150 tons of catalyst. The catalyst feed rate is 6
to 9.5 tons/s, and the gas recycle ratio is 2: 1.
Packed Bed. The packed-bed reactor used at the Sasol plant to carry out Fis-
cher-Tropsch synthesis reaction is shown in Figure El-5.3. Synthesis gas is fed at a
rate of 30,000 m3/h (STP) at 240°C and 27 atm to the packed-bed reactor. The reac-
tor contains 2050 tubes, each of which is 5.0 cm in diameter and 12 m in length.
The iron-based catalyst that fills these tubes usually contains K,O and SiO, and has
Use to produce wax a specific area on the order of 200 m2/g. The reaction products are light hydrocar-
for candles and bons along with a wax that is used in candles and printing inks. Approximately 50%
printing inks. conversion of the reactant is achieved in the reactor.
s J
( 1- Gas inlet
Steam heater
Steam
iniector -Steam outlet
bundle
Figure a-5.3 Packed-bed reactor. (Schematic and photpgraph dourtesy of
Sasol/Sastech W Limited.)
The aim of the preceding discussion on commercial reactors is to give a
more detailed picture of each of the major types of industrial reactors: batch,
semibatch, CSTR, tubular, fixed-bed (packed-bed), and fluidized-bed. Many
variations and modifications of these commercial reactors are in current use;
for further elaboration, refer to the detailed discussion of industrial reactors
given by Walas.
S. M. Walas, Reaction Kinetics for Chemical Engineers (New York: McGraw-Hill,
1959), Chap. 1 1.