Page 259 - Engineered Interfaces in Fiber Reinforced Composites
P. 259

240               Engineered  interfaces in fiber reinforced  composites

                     composite is not simply the sum of the weighted contributions by  the constituents,
                     but  is governed more  importantly  by  the extent  of  synergistic energy absorption
                     processes  through  various  toughening  mechanisms,  depending  on the  nature  of
                     physicochemical bonding and elemental constitutions at the fiber-matrix  interface
                     region.
                       There are many theoretical and experimental studies carried out on the fracture
                     behavior  and  toughening  mechanisms  in  fiber  reinforced  composites.  When  a
                     composite having internal cracks is loaded, there is a highly strained region at the
                     crack tip, the so-called fracture process zone (FPZ) or damage zone, where failure
                     mechanisms of various kinds take place before the cracks propagate. Summaries of
                     the  failure  mechanisms  in  polymer  matrix  composites  can  be  found  in  many
                     references including Kelly (1973), Marston et al. (1974), Atkins (1975) and Harris
                     (1980), and these are reviewed recently by Kim and Mai (1991a, b,  1993). Reviews
                     on  failure  mechanisms  are  also  available  for  MMCs  (Ochiai,  1989;  Taya  and
                     Arsenault,  1989; Clyne  and Withers,  1993), CMCs (Davidge,  1989; Warren  and
                     Sarin, 1989; Evans,  1989; Ruhle and Evans,  1989; Chawla, 1993), and cementitious
                     fiber composites (Mai,  1985; Cotterell and Mai,  1996).
                       Many  fracture  toughness theories  of composite materials have  been  developed
                     mainly for those with unidirectional fibers. The various origins of fracture toughness
                     in  composites may  be  characterized  by  considering  the  sequence of  microscopic
                     fracture  events that lead  to crack propagation  macroscopically  under  monotonic
                     increasing loads.  The cracks in composites can propagate preferentially along the
                     fiber-matrix  and laminar interfaces (i.e. longitudinal splitting) or transversely right
                     through the fiber and matrix (i.e. transverse cracking), depending on the properties
                     of the interface relative to the fiber and matrix. The criteria for these two opposing
                     fracture phenomena  are given in  Section 6.4. Consideration  of  a  microcomposite
                     model  shown  in  Fig.  6.1  (Harris,  1980) makes  it  most  convenient  to isolate  the
                     individual  micromechanisms  of  toughening.  When  a  crack  present  in  the  matrix
                     approaches an isolated fiber, the following failure mechanisms may be expected to
                     take place:
                       (1)  matrix fracture,
                       (2)  fiber-matrix  interface debonding,
                       (3)  post-debonding friction,
                       (4) fiber fracture,
                       (5)  stress redistribution,
                       (6) fiber pullout.
                       The underlying physical bases of these toughening mechanisms are presented in
                     the following sections, and the corresponding equations  are summarized  in Table
                     6.1.  All  these  mechanisms,  except  fracture  of  fibers  and  matrix,  are  a  direct
                     consequence  of shear  failure at the imperfectly bonded  fiber-matrix  interface.  In
                     conjunction with these mechanisms, fiber bridging, crack deflection and bifurcation,
                     and microcracking  also  take place  depending on the  strength  of  the constituents
                     relative to that of the interface, microstructure of the composite constituents, and
                     the loading configuration of the composite structure.
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