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354                            Enhanced Oil Recovery in Shale and Tight Reservoirs


          10 ft matrix block being 1 mD and oil-wet. The osmotic pressure reached 40
          psi after 30 years imbibition. Oil started to flow from the matrix to the
          fracture at 20 years. The oil recovery from the matrix reached 35% after
          40 years. 5% membrane efficiency was used. Note that the maximum os-
          motic pressure from their model is more than two times the average pressure
          (0.128 MPa or 18.9 psi) from Neuzil and Provost’s (2009) review mentioned
          earlier. Such osmotic pressure should be much lower than the capillary
          pressure. To make oil be able to flow out of matrix, they used almost
          zero capillary pressure for the oil-wet matrix which is presented in
          Fig. 12.12. It seems that the significance of the effect of osmotic pressure
          on oil recovery in a shale or tight formation is questionable. However, in
          a separate paper (Fakcharoenphol et al., 2016), their simulation shows that
          the osmotic effect was more significant than the capillary effect on increasing
          gas rate and decreasing water production.
                                                      2þ
                                                            þ
             Some shale formations are oil-wet owing to Ca /Na bridging of oil
          molecules to the negatively charged clay surface. When low-salinity water
                                       2þ
                                            þ
          invades the high-salinity zone, Ca /Na will detach from the rock surface.
          As a result, the surface may become more water-wet, resulting in the in-
          crease in oil relative permeability and decrease in residual oil saturation (Kur-
          toglu, 2013). More possible mechanisms for low-salinity waterflooding are
          summarized in Sheng (2014).
             Because of osmosis, some water will be held in the high-salinity zone of a
          shale or tight formation. That could be one of the reasons to explain less flow



          (A)                              (B)
             1.0                             1000
            Relative permeability, fraction  0.6  Oil-wet  Capillary pressure, psi  600  Water-wet
             0.8
                                              800


                                              400
             0.4
             0.2

             0.0                Water-wet     200 0    Oil-wet
               0.0  0.2  0.4  0.6  0.8  1.0      0.0  0.2  0.4  0.6  0.8  1.0
                   Water saturation, fraction        Water saturation, fraction
          Figure 12.12 (A) Relative permeability, (B) capillary pressure used in Fakcharoenphol
          et al.’s (2014) model.
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