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358                            Enhanced Oil Recovery in Shale and Tight Reservoirs


                 1
                         MeOH evaporated
               0.8       MeOH removed
                         MeOH expelled
              PV Liquid Removed  0.6



               0.4


               0.2

                 0
                 0.1        1         10        100       1000     10000
                                          N PVg
          Figure 12.15 Liquid (methanol) removed from Berea sandstone core by displacement
          and evaporation (p mean ¼ 1.1 atm., k ¼ 327 mD, and the core length 7.6 cm) (Mahadevan
          and Sharma, 2005).

          the liquid (brine) removed from a Texas Cream limestone core by displace-
          ment and evaporation. Evaporation started to remove brine when the flood
          gas volume reached 1000 pore volumes (N PVg ). Fig. 12.15 shows the meth-
          anol removed from a Berea sandstone core by displacement and evaporation.
          Evaporation started to remove brine when the flood gas volume reached
          60 N PVg . In this case, the rock permeability was high, and the volatile meth-
          anol was used. These conditions are favorable to evaporation (Mahadevan
          and Sharma, 2005). It can be predicted that in shale and tight reservoirs, it
          will take much longer time for the evaporation to start to show up.

          12.3.6 Permeability jail
          Many field cases show that the connate water saturation is immobile at very
          high saturations in low permeability reservoirs; within a large range of
          middle saturation, neither gas nor water could flow (Shanley et al., 2004).
          They term this range of saturation “permeability jail”. Ojha et al. (2017)
          estimated relative permeabilities for shale cores using nitrogen adsorption-
          desorption data. Their data show that water cannot move for water saturation
          higher than 50%. Based on these facts, we may hypothesize that during the
          fracturing operation, high pressure and saturation of fracturing fluid force
          the fracturing fluid (water) to move deep into a formation, with help of water
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