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152 Principles and Methods
Adsorption
As it has been previously discussed, the chemical reactivity of nanopar-
ticle surface sites is an important issue for many industrial applications
as well as for environmental concerns. Chemical reactivity is strongly
influenced by the large ratio of surface atoms to nonsurface atoms.
Adsorption properties of nanoparticles from an environmental per-
spective are discussed in Chapter 10. The adsorption mechanisms of mol-
ecules or atoms on the nanoparticle surface can be described using many
of the techniques previously covered and using other techniques such
as infrared spectroscopy and NMR.
References
Auffan M., Decome L., Rose J., Orsiere T., Demeo M., Briois V., Chaneac C., Olivi L., Berge-
Lefranc J.-L., Botta A., Wiesner M. R., and Bottero J.-Y. (2006) In Vitro Interactions
between DMSA-Coated Maghemite Nanoparticles and Human Fibroblasts: A
Physicochemical and Cyto-Genotoxical Study. Environmental Science and Technology.
Bazin D., Sayers D., Rehr J. J., and Mottet C. (1997) Numerical Simulation of the Platinum
LIII Edge White Line Relative to Nanometer Scale Clusters. Journal of Physical
Chemistry B.(101), 5332–5336.
Berne B. J. and Pecora R. (1976) Dynamic Light Scattering. Wiley.
Berne W. (1996) Light Scattering: Principles and Development.
Bottero J., Manceau A., Villieras F., and Tchoubar D. (1994) Structure and Mechanisms
of Formation of FeOOH(Cl) Polymers. Langmuir 10(1), 316–319.
Chemseddine A., Fieber-Erdmann M., Holub-Krappe E., and Boulmaaz S. (1997) XAFS
Study of Functionalized Nanoclusters and Nanocluster Assemblies. Zeitschrift für
Physik D Atoms, Molecules and Clusters 40(1–4), 566–569.
Chemseddine A. M., Moritz T. (1999) European Journal of Inorganic Chemistry 2, 235.
Choi H. C., Jung Y. M., and Kim S. B. (2005) Size Effects in the Raman Spectra of TiO2
Nanoparticles. Vibrational Spectroscopy 37, 33–38.
Combes J.-M., Manceau A., Calas G., and Bottero J.-Y. (1989) Formation of Ferric Oxides
from Aqueous Solutions: A Polyhedral Approach by X-ray Absorption Spectroscopy. 1.
Hydrolysis and Formation of Ferric Gels. Geochimica and Cosmochimica Acta 53(3),
583–594.
Denaix L., Lamy I., and Bottero J.-Y. (1999) Structure and Affinity Towards Cd2 , Cu2 ,
Pb2+ of Synthetic Colloidal Amorphous Aluminosilicates and Their Precursors. Colloids
and Surfaces A: Physicochemical and Engineering Aspects (158), 315–325.
Fernandez-Garcia M., Martinez-Arias A., Hanson J. C., and Rodriguez J. A. (2004)
Nanostructured Oxides in Chemistry: Characterization and Properties. Chemical
Review 104, 4063–4104.
Ferraro J. R. and Nakamoto K. (1994) Introductory Raman Spectroscopy. Academic Press.
Fontaine A. (1993) Interactions of X-rays with Matter: X-ray Absorption Spectroscopy. In
Neutron and Synchrotron Radiation for Condensed Matter Studies, (eds. Baruchel J.,
Itodeau J.-L., Lehmann M. S., Regnard J. R., and Schlenker C.). Les Editions de
Physique—Springer Verlag.
Frenkel A. I., Hills C. W., and Nuzzo R. G. (2001) A View from the Inside: Complexity in
the Atomic Scale Ordering of Supported Metal.
Nanoparticles, Dextran and Albumin Derivatised Iron Oxide. The Journal of Physical
Chemistry B 105(51), 12689–12703.
Glatter O. and Kratky O. (1982) Small-Angle X-ray Scattering. London: Academic Press.
Greegor R. and Lytle F. (1980) Morphology of Supported Metal-Clusters—Determination
by EXAFS and Chemisorption. Journal of Catalysis 63(2), 476–486.
Helmerich A., Raether F., Peter D., and Bertagnoly H. (1994) Structural Studies on an
ORMOCER System Containing Zirconium. Journal of Material Science 29, 1388–1389.