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180 Essentials of Physical Chemistry
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(20) 11. Consider data for the reaction: H 2 O 2 þ Na 2 S 2 O 3 [H ] ) 2H 2 O þ Na 2 S 4 O 6
Time (min) 16 36 43 52 at T ¼ 0, [H 2 O 2 ] ¼ 0.0368
[(S 2 O 3 ) ] 0.01030 0.00518 0.00416 0.00313 and [(S 2 O 3 ) ] ¼ 0.0204
2
2
How long will it take until [(S 2 O 3 ) ] ¼ 0.0030? (Answer: 53.3 min)
2
BIBLIOGRAPHY
Houston, P. L., Chemical Kinetics and Reaction Dynamics, McGraw Hill, Boston, MA, 2001.
Lesk, A. M., Introduction to Protein Architecture, Oxford University Press, London, 2000.
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16. Kimball, J., Enzyme kinetics, http:==users.rcn.com=jkimball.ma.ultranet=BiologyPages=E=EnzymeKi-
netics.html Special thanks to Prof. John Kimball of Harvard for contributing the data and graphs related
to the reaction of o-diphenol oxidase (catechol oxidase) with catechol. More is available from his site at
Kimball’s Biology Pages, http:==biology-pages.info