Page 290 - Fiber Fracture
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FRACTURE OF HIGHLY ORIENTED, CHAIN-EXTENDED POLYMER FIBRES           273



















             Fig. 6. (a) Crack propagation with bifurcation. (b) Broken fibre showing an end of  type (a) on the left and
             of type (b) on the right. (c) If an inner bifurcation grows faster than an outer one, the multiple splitting on
             one end would point away from the break and not towards the break.


               Fig. 8 shows that long axial splits also occur in the tensile fracture of a high-modulus
             polyethylene fibre.

             Creep Rupture

               Time  is  always a  factor  in  determining the  effective strength of  polymer  fibres.
             Higher strengths occur in ballistic impact resistance and lower strengths in  long-term
             loading situations. Even when another fatigue mechanism is the main cause of failure,
             the final stage leading to breakage is creep rupture.
               The time-dependent behaviour is different in the two types of highly oriented, chain-
             extended polymer fibres. Table 1 gives the results of studies in FTBRE TETHERS 2000
             (1995), which were made because creep rupture is a concern in deep-water mooring
             of oil-rigs. The low-load creep in aramid fibres is due to a straightening of the initial
             structure. It reduces in rate, even on a logarithmic scale, with time and is not a source of
             creep rupture. In Vectran, the creep is less and is absent after 10 days under load.
               HMPE fibres show high creep and in the worst cases break after a few days under
             moderate loads.  Table  1  shows that  there  are  big  differences in  creep  response  in


             Table 1. Creep properties from Fibre Tethers 2000
                               o/c creep 1  min to 100 days   Days to rupture
             ~~            ~
             8 of break load    15         30               15          30
             Kevlar 29          0.13        0.2 I         >357        2213
             Kevlar 49          0.09        0.08          >217        >217
                                  1
             Twaron 1000        0.2         0.25          >357        2214
             Vectran            0.06        0.09           > 13       >218
             Spectra 900        15.8       break            182          4
             Spectra 1000       7.96       break           33  I        28
             Dyneema SK60       I .05       6.0           2354         I23
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