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82   SEQUENCE STRATIGRAPHY OF UNCONVENTIONAL RESOURCE SHALES

            by  Donovan and Staerker, 2010) of the underlying Buda   studies have subdivided the LaLuna into the lower Salada
            Limestone. Above this interval, the gamma ray log response   (black shales, black mudstones, black calcareous claystone,
            diminishes progressively upward, indicating an HST. Super­  black limestone layers with internal pyritized concretions),
            imposed on this second‐order sequence are a number of   middle Pujamana (claystone, mudstone, gray shale, and
            third‐order sequences; three additional SBs and mfss have   cherts), and upper Galembo (calcareous shales with lime­
            been recognized on the outcrop and extended to subsurface   stone layers and nodules) members. There are no well logs
            wells; more high‐frequency sequences occur throughout the   available, but based upon geochemical analysis of outcrop
            Eagle Ford at the outcrop and subsurface sites.        samples, a preliminary sequence  stratigraphic framework has
                                                                 been established (Fig. 4.15) (Torres‐Parada, 2013).
                                                                   Included in this framework is a residual hydrocarbon
            4.7.4  LaLuna Formation (upper Cretaceous)
                                                                 potential (RHP) plot (Fang et al., 1993) that allows strati­
            The LaLuna Formation is the main hydrocarbon source   graphic intervals to be interpreted as varying upward from
            rock  in the Middle Magdalena Valley basin of Colombia,   oxic to anoxic or vice versa. In this case, the entire LaLuna
            South America. It is currently being investigated as uncon­  Formation records a lower interval of high and variable,
            ventional resource shale. Limited outcrop and subsurface   overlain by an upper, interval of lower TOC. Both TOC



               Fm    Litha
                                           TOC %wt                                      RHP
               Umir       0 0  1  2  3  4  5  6  7  8  9 10 11 12 13   8    7   6    5    4   3    2    1   0
                  galembo member  100            TST     SB/TSE  Galembo    FS
                LaLuna                    HST    TST



                                               HST       SB/TSE
                        200                                               FS
                                                 T
                                                 TST
                                                         SB/TSE         FS
                                                 TST
                 LaLuna pujamana member  400   LST          TOC Pujamana

                        300



                        500


                        600                   HST        SB/TSE


                        700                     HST  TST   SB/TSE       FS
                 LaLuna salada member  800   HST   TST   SB/TSE    Salada    FS





                        900

                       1000                                               FS
                  Legend                           TST
                  Calcareous shale
                  Coaly shale lamina
                  Calcareous limestone                           Oxic to anoxic      Anoxic to oxic
                  Chert
                  Siltstone
                  Black siliceous shale
                  Calcite nodules
            FIGurE  4.15  LaLuna Formation (Colombia) outcrop sequence stratigraphy, determined from measured stratigraphic sections,  TOC
            content, and RHP (see text) calculations. The three members of the LaLuna are the lower Salada member, the middle LaLuna member, and
            the upper Galembo member. These members are subdivided into a series of high‐frequency sequences, in all but one interval, comprising TST
            and HST bounded by SB/TSE. Permission to publish this figure was granted by E. Torres‐Parada (2013).
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