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132   PETROPHYSICAL EVALUATION OF GAS SHALE RESERVOIRS

                10                                                Low



                8
               W TOC  from pulsed neutron (wt%)  6    k assumed  <   real  assumed   k assumed  =   real  Young’s modulus (GPa)  BI (%) 0
                                 k
                                                     k



                4
                                               >

                                                 real
                                          k
                                                 k
                2
                                                                                                             100
                                                                 High
                                                                      Low                                   High
                0                                                                     Poisson’s ratio
                  0       2       4      6       8      10       FIGURE 6.14  Cross plot of Young’s modulus versus Poisson’s
                             W TOC  from NMR (wt%)               ratio showing change in brittleness index qualitatively with Young’s
                                                                 modulus and Poisson’s ratio.
            FIGURE 6.13  Correcting assumed kerogen density using cross‐
            plot analysis between  W TOC  from NMR and  W TOC  from pulsed
            neutron mineralogy log.                              brittleness index by combining Poisson’s ratio, ν, and Young’s
                                                                 modulus, E. These two components are combined to reflect
                                                                 the rock strength to fail under stress (Poisson’s ratio) and to
            In some documents, kerogen and TOC are (mistakenly) used   maintain a fracture (Young’s modulus) once the rock fractures
            interchangeably, which is not correct based on their geo­  (Rickman et al., 2008). Therefore, brittle shales should have
            chemical definitions. Computed kerogen volume from for­  low Poisson’s ratio and high Young’s modulus (Fig. 6.14).
            mula 6.21 can be converted to TOC volume:
                                                                 The dynamic Young’s modulus and Poisson’s ratio are calcu­
                               V TOC  KC k             (6.23)    lated from compressional and shear velocities using the fol­
                                                                 lowing formulas:
            C  is a constant value between 0.7 and 0.85 and depends on
             k
            the maturity level and type of kerogen. Finally, TOC volume              V 2  3 V  2  4 V 2
            percentage can be converted to a weight fraction TOC using          E     s  2  p  2  s         (6.25)
            the following formula to compare it with TOC from core                     V p  V s
            data or the pulsed neutron mineralogy tool:                               V p 2  2 V s 2

                             W TOC   k  V TOC          (6.24)                         2  V p 2  V s 2       (6.26)
                                    m
                                                                 where ρ is the bulk density and V  and V  are compressional
                                                                                           p
                                                                                                 s
            Because kerogen density is approximately half of the matrix   and shear wave velocities, respectively. Regarding the stated
            density  (ρ  = 1.1–1.4  g/cm   and  ρ  = 2.6–2.8  g/cm ),  TOC   relationships between Young’s modulus and Poisson’s ratio
                                                     3
                                 3
                    k
                                        m
            weight percentage should be half of TOC volume percentage.   with brittleness of the shale layers, the E and ν are normal­
            The assumed value for ρ  can be determined by comparing   ized using following formulas:
                                k
            W TOC  from NMR with W TOC  from the pulsed neutron miner­
            alogy tool. Regarding formula 6.21, if the assumed value of                  EE
                                                                                             min
            ρ  is less than the real value, estimated K, V TOC , and conse­      E brittle  E  E            (6.27)
             k
            quently W TOC  from NMR would be less than the determined                    max  min
            value from the mineralogy log and vice versa. If the assumed                    max             (6.28)
            value of kerogen density is correct, then these two curves            brittle
            should provide similar results (Fig. 6.13).                                  min  max
                                                                 The brittleness index (BI) is then defined as average of E
            6.4.2.5  Determination of Brittleness Index  Brittle shales   and ν  :                            brittle
            are more likely to be naturally fractured and will also be more   brittle
            likely to respond well to hydraulic fracturing treatments.        BI     E brittle  brittle  100  (6.29)
            Rickman et al. (2008) and Grieser and Bray (2007) defined a         sonic    2
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