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166     Gas Wettability of Reservoir Rock Surfaces with Porous Media





                            reducing energy. At this time, the contact angle is 0 , θ , 90 , and cos θ . 0,
                            water-displacing-gas front is concave, the direction of water-displacing-gas is
                            upright. The capillary force is P c . 0 and is the power of water-displacing-gas.
                            On the contrary, when σ solid-gas , σ solid-water , solid/water interface displacing
                            solid/gas interface is a process of energy increase. At this time, contact angle is


                            90 , θ , 180 , and cos θ , 0, water-displacing-gas front is convex, direction of
                            water-displacing-gas is upright. The capillary force is P c , 0 and is the
                            resistance of water-displacing-gas.
                            5.1.1.2 EXPERIMENT

                            5.1.1.2.1   Experiment Material and Apparatus
                            Experiment materials: distilled water, fluorocarbon polymer gas-wetting alter-
                            ation agent, quartz slides, quartz capillary (φ 5 0:8mm, L 5 40 mm).
                            Experiment apparatus: The contact angle of liquid drops in air is measured
                            with JC2000D3 contact angle meter. Under quasistatic conditions, the experi-
                            ment equipment for water-displacing-gas in capillaries is as shown in Fig. 5.2.

                            5.1.1.2.2   Experiment Method
                               1. Fluorocarbon polymer gas-wetting alteration agent solutions with mass
                                 concentration of 0%, 0.2% and 8%, respectively, were prepared.
                               2. A quartz slide and a capillary were soaked in gas-wetting alteration
                                 agent solutions of same concentration. After being immersed for
                                 4 hours, they were then taken out and dried, and kept as the experiment
                                 sample group.
                               3. The contact angle of water (θ water ) was measured with sessile drop
                                 method for the quartz slide treated by gas-wetting alteration agent solu-
                                 tion of certain concentration, to evaluate gas wettability of the quartz
                                 slide surface.

                                                       Industrial-grade camera


                                  Stereo microscope
                                                                    Data cable

                                                                             Computer
                       Injector



                                         Light
                                Peristaltic pump
                                                   Platform     Graduated cylinder
          FIGURE 5.2
          Microscopic experiment equipment.
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