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118                                                             Chapter 5

             TABLE 5-I

             Results of multiple regression analysis (forced simultaneous inclusion of independent variables
             and forced through the origin) using log e -transformed stream sediment Cu and Zn data (n=102; see
             Figs. 2-7A and 2-9A, respectively) as dependent variables and areal proportions of lithologic units
             (see Fig. 1-1) in sample catchment basins as independent variables.

               Dependent   Anti-log e  of regression coefficients of independent variables   R
                                                                               2
                variable     Basalt    Limestone    Phyllite   Quartzite
                  Cu         49.2        50.6        48.7        29.8        99.58
                  Zn         25.2        84.9        41.9        11.1        96.21


                                              2
             multiple regression models  with high  R , although  the models  become  multiplicative
             rather than additive. Logarithmic transformation of  uni-element concentration data
             results, however, in regression coefficients that are usually positive and easy to interpret.
             Whether raw or log-transformed uni-element concentration data are used, statistical tests
             of significance of the regression are inappropriate if the stream sediment sampling
             density is high and/or if the stream sediment uni-element concentration data exhibit
             some degree of spatial autocorrelation and thus are not independent (Bonham-Carter et
             al., 1987).
                For the stream sediment Cu and Zn data shown in Figs. 2-7A and 2-9A, respectively,
             Table 5-I  shows the  regression coefficients for the lithologic  units (see Fig.  1-1)
             occurring in the sample catchment basins. The regression analysis was performed after
             log e-transformation  of the data to reduce  asymmetry in their empirical density
             distributions. The regression coefficients of the independent variables given in Table 5-I
             are transformed  back to  normal values to illustrate that they represent average  uni-
             element concentrations in individual lithologic units. The average Cu concentrations (in
             ppm) in each lithologic unit, except quartzite, are more or less uniform at about 50 ppm,
             while the average Zn concentrations (in ppm) in each lithologic unit are different. The
                      2
             values of R  indicate that the Cu and Zn concentrations in stream sediments in the area
             are mostly entirely due to lithology, although about 4% of  variability in Zn is not
             accounted for by lithology. Consequently, the spatial distributions of local background
             Cu and Zn concentrations in stream sediments per sample catchment basin, as estimated
             according to equation (5.4), reflect mostly the patterns of the lithologic units (Fig. 5-1).

             Analysis of weighted mean uni-element concentrations due to lithology
                Local background uni-element concentrations  due to lithology in every sample
             catchment basin can also be estimated by first calculating a weighted mean uni-element
             concentration  M j in each of the  j (=1,2,…,m) lithologic units in  i (=1,2,…,n) sample
             catchment basins, thus:

                            n
                   n
             M  j = ¦ = i 1 Y i X ˆ ij  ¦ = i 1 X ˆ ,                            (5.5)
                                ij
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