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Geochemical Remote Sensing of the Subsurface
           Edited by M. Hale
           Handbook of Exploration Geochemistry, Vol. 7 (G.J.S. Govett, Editor)
            9   Elsevier Science B.V. All rights reserved                       133
           Chapter 5





           LIGHT HYDROCARBONS FOR PETROLEUM AND GAS PROSPECTING

           V.T. JONES, M.D. MATTHEWS and D.M. RICHERS






           INTRODUCTION

              Surface  geochemical prospecting  for hydrocarbons includes  a myriad of  techniques
           ranging  from  the  direct  detection  of  hydrocarbons  escaping  from  subsurface
           accumulations and source beds to identifying secondary responses in the soils, rocks and
           biota  in  proximity  to  such  accumulations  or  source  beds.  In  the  historical  sense,  the
           observation  of visible  seepage  of hydrocarbons  is  the  oldest  method  of prospecting  for
           petroleum. Drake's historic well near Titusville, Pennsylvania,  was drilled on the basis of
           a seep in the adjacent creek bed. The relationship of such "macroseeps" to reservoirs was
           well  established  by  Link  (1952),  who  stated:  "A  look  at  the  exploration  history  of the
           important oil areas of the world proves conclusively that oil and gas  seeps gave the  first
           clues to most oil-producing  regions. Many great oil fields are the direct result of seepage
           drilling".  In this respect,  few would argue that the presence  of a macroseep  indicates  the
           presence  of petroleum  migration  or  surface  source  beds.  Microseeps,  or  smaller  scale
           macroseeps,  also occur because of the physical continuity necessarily imposed by nature.
           These  are  invisible  seeps,  usually  detectable  only  by  sensitive  instruments  or  by  the
           visible result of their effect on the near-surface environment. These microseeps, although
           perhaps not as obvious or dramatic as macroseeps, are just as valid for the exploration of
           undiscovered  reserves.  This  chapter presents  the  conceptual  and practical  application  of
           microseepage  detection  and  interpretation in the  evaluation of areas  for their subsurface
           hydrocarbon potential.
              Five  factors  are  necessary  to  form  a hydrocarbon reservoir.  These  are:  (1)  a  source;
           (2)  a  reservoir  in  which  the  hydrocarbons  can  collect  or  concentrate;  (3)  a  means  of
           trapping these  fluids  in this reservoir (a seal);  (4) a pathway to the reservoir (migration);
           and (5) the proper timing such that the  source,  reservoir,  seal and migration pathway are
           present when required.  Near-surface  seepage  of thermogenic  hydrocarbons indicates  the
           subsurface  presence  of a mature  source  and  migration pathway.  It  also  suggests  that,  if
           the hydrocarbons are reservoired, the seal is imperfect. This is true of both macroseepage
           and microseepage. Patton and Manwaring (1984) found that even in an area of extensive
           evaporites  (Hugoton  Field,  Kansas),  the  seal  was  not  perfect,  and  that  microseepage
           could be detected in the vicinity of the Syracuse Fault.
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