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18                           Geothermal Energy: Renewable Energy and the Environment


                               1.4

                               1.2  Less than 300 micron
                                        grain size
                              Thermal conductivity  (W/m–K)  0.8  Greater than 300 micron
                               1.0





                               0.6
                                                           grain size
                               0.4

                               0.2


                               0.0
                                 0.0    2.0   4.0   6.0    8.0   10.0  12.0
                                              Saturation (volume %)

            FIGUre  2.3  Thermal  conductivity  as  a  function  of  saturation  for  sands  of  different  grain  size.  (From
            Manohar, K., Ramroop, K., and Kochhar, G., West Indian Journal of Engineering, 27, 2005.)


            to a hundred times faster than a mineral. This also suggests that the rock enclosing a magma body
            will behave as an insulating medium, transferring the heat away from the cooling molten rock at a
            relatively slow rate.
              Complicating  these  relationships  is  the  fact  that  rocks  and  soils  are  porous  materials.  The
            amount  of  porosity  and  its  properties  can  vary  significantly  (see  discussion  in  Chapter  4).  In
            general, the greater the porosity the lower the thermal conductivity. The extent to which thermal
            conductivity  and  diffusivity  are  diminished  by  porosity  will  depend  upon  what  fills  the  pore
            space. Water and air are the most common pore-filling materials, and their respective thermal
            conductivities (Figure 2.2) are significantly different. Thus, for two rocks or soil samples in which
            all other things are equal, thermal conductivity will be higher in materials in which all of the pore
            space is water-filled (saturated), compared to materials in which some or all of the pore space is
            air-filled.
              In Figure 2.3, the effect of saturation in quartz sand on the thermal conductivity is  dramatically
            apparent.  There  are  several  points  relevant  for  geothermal  considerations  that  emerge  from
            Figure 2.3. The first point is that the relationship between saturation and k  is not linear. This results
                                                                      th
            from the fact that the surface tension of water causes it to distribute itself primarily along contact
            points and junctions between sand grains, rather than evenly and uniformly within a pore space, in
            contrast to what a gas would do. As a result, the ability of thermal energy to be transmitted at grain
            contact points rapidly improves with the addition of a small amount of water. The rate at which
            thermal transmissivity improves quickly falls between 10% and 20% saturation.
              A second point evident from Figure 2.3 is that pore size also affects how saturation influences
            k . This effect is a consequence of the fact that the number of contact points between grains, per
             th
            unit volume, depends directly on the size of the grains. Since there are more contact points per unit
            volume for a smaller grain size, k  will increase more rapidly with increasing saturation in fine sand
                                      th
            than coarse sand.
              Both of these points make it clear that efficient use of geothermal energy must be based on thor-
            ough knowledge of the properties of the geological materials at the site that will be developed. Such
            knowledge should include thermal conductivity measurements that have been made in a laboratory
            on material that is as little disturbed from its natural state as possible. This is true for applications
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