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Sources of Geothermal Heat: Earth as a Heat Engine                           19


            that are dependent on the thermal properties of near-surface materials (e.g., ground source heat
            pump installations; discussed in Chapter 11), as well as for applications involving power generation
            using geothermal energy from deep bedrock sources.
              Although the thermal conductivity of minerals is not insignificant, minerals are poor con-
            ductors  of  heat  compared  to  metals.  Aluminum,  for  example,  has  a  thermal  conductivity  of
            about 210 W/m-K at room temperature and iron has a thermal conductivity of about 73 W/m-K.
            Minerals conduct heat at rates that are, in general, one to two orders of magnitude less than those
            for common metals (Table 2.3). Although thermal conductivity has a strong influence on the local
            thermal properties of a geothermal site, the amount of heat available at a site is a reflection of
            another heat transfer process in the Earth that derives from the relatively low thermal conduc-
            tivity of minerals. That heat transfer process is convection, which is the dominant mode of heat
            transfer in the Earth.


            convecTion
            Conductive heat transfer occurs without movement of mass. However, a warm mass of any material
            flowing into a cooler region is also a means for accomplishing heat transfer. If, for some physical
            reason, the flow of the heated mass into the cooler region is not accompanied by any heat conduc-
            tion, the process is called advection. Under most circumstances in the Earth, however, the move-
            ment of the mass will occur as heat is simultaneously being conducted away. This combined process
            of heat being transferred by both mass movement and heat conduction is called convection.
              In the presence of gravity, materials that have a lower density will tend to rise above materials of a
            higher density. In a planetary body composed of randomly distributed materials of differing  density,
            an equilibrium state will eventually be achieved when all of the materials are ordered sequentially
            from the highest density material in the center of the body to the lowest density material at the outer
            edge of the body. This arrangement of densities is called density stratification. Density stratification
            will occur spontaneously over time provided some or all of the materials are capable of flow. The
            rate at which this will occur depends upon the viscosities and density differences of the materials
            involved. The early Earth achieved this state of density stratification within a few tens of millions
            of years, as previously discussed. However, this condition did not result in a static planet because it
            was not a stable configuration.
              Viscosity is the resistance of a material to flow when stressed. Materials with a high viscosity
            are materials that, because of their molecular structure, possess high internal friction. Fluids, such
            as cold honey or molasses, have a high viscosity, compared to water or air. The resistance to flow is
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            measured in units of Pascal-seconds (Pa × s). One Pa × s is equivalent to 1 m × kg × s /m , which is
                                                                                   2
            a measure of applied stress and the resulting deformation (or strain) it experiences. The range of vis-
            cosities materials possess is shown in Table 2.4. Note that many materials that seem incapable of flow
            at room temperature conditions (such as portions of the solid mantle of the Earth) do, in fact, have
            high but significant viscosities at high temperatures and pressures that are important over geological
            time scales.
              In the absence of an energy source, a density-stratified Earth is a stable configuration for the
            distribution of materials that compose the Earth. However, the hot, molten outer core is a very large
            energy source that continuously heats the base of the mantle. As previously noted, the minerals
            that compose the Earth are poor thermal conductors. The mantle, therefore, is essentially a thermal
            insulator surrounding the core. As the base of the mantle heats, the minerals immediately adjacent
            to the core expand, thus becoming less dense. In addition, they also become less viscous. As this
            happens, portions of the thermally perturbed lower mantle begin to experience gravitational insta-
            bility since they become relatively buoyant compared to the overlying, cooler and denser mantle.
            Eventually, the combined effect of decreasing density and viscosity overcomes the resistance to
            flow and the heated lower mantle begins to rise buoyantly toward the surface. It is at this point that
            convection starts.
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