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5.10 Stralsund (Germany)  291
                         assumed period of operation of the geothermal heating plant is 80 years. Changes
                         in porosity can be calculated without difficulty from the reaction rates of the mineral
                         components knowing their molar volumes. However, it is not as straightforward to
                         estimate the associated changes in permeability because permeability depends not
                         only on the bulk porosity but also strongly on the structure of the pore space. We
                         applied the so-called ‘‘pigeon hole’’ model especially suited for sedimentary rocks
                         of (Pape et al., 1999). This model yields petrophysically justified relations between
                         the various geometric, storage, and transport parameters of these reservoir rocks.
                         Like other fractal models, it is based on the observation that the shape of the
                         internal surface of rock pores follows a self-similar rule.

                         5.10.3
                         Long-Term Development of Reservoir Properties

                         The study of the long-term behavior of the reservoir properties of the Stralsund
                         deep aquifer requires, as far as possible, a quantitative separation of the single
                         contribution of the various processes involved from the hydraulic changes in
                         the aquifer that occur as a result of reinjection. Reinjection of cooled water of
                         higher viscosity than the natural reservoir fluid leads to a continuous reduction of
                         the injectivity (Figure 5.34). This effect is partially balanced by thermally induced
                         mineral reactions. Dissolution of anhydrite in the vicinity of the injection well dom-
                         inates the effect of anhydrite precipitation at the propagating thermal front leading
                         to a net increase of injectivity (K¨ uhn et al., 2002). Observed calcite precipitation
                         around the injection well and dissolution at the thermal front are too small to alter
                         reservoir properties significantly. Coupled numerical simulation indicates that the

                            1490

                            1470
                           Hydraulic head (m)  1450  Nonreactive case (fluid flow + heat transfer)


                            1430

                            1410
                                             Reactive case (fluid flow + heat transfer + chemical reactions)
                                             Isothermal reinjection (fluid flow)
                            1390

                            1370
                                 0     10    20     30    40     50    60     70    80
                                                       Time (years)

                         Figure 5.34  Temporal evolution of the pressure head at the
                         injection well shown as a hydraulic head during 80 years of
                         reservoir exploitation (K¨ uhn et al., 2002).
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