Page 59 - Handbook Of Multiphase Flow Assurance
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54                            3.  PVT and rheology investigation

                                      1200
                                     Correlation  Boiling Temperature, K  800
                                      1000




                                       600
                                       400

                                       200

                                         0
                                          0    200   400   600  800   1000  1200
                                                 Data Boiling Temperature, K
                 FIG. 3.6  Comparison of boiling temperature from correlation vs from data.
                   The correlation performs fairly well, within ±20% error vs data as shown in Fig. 3.6.
                   Density can be related to carbon number either by method of Whitson and Brule (2000) or
                 Pedersen (1989).
                   Additional correlation in Fig. 3.7 for 115 n-alkanes, isoalkanes and aromatics is proposed,
                 applicable to C 5 +:
                                                        (
                                     
                                                               #
                                  SG at 20 ° C = 0 0661 ∗  Lncarbon ) + 059  for C5 +
                                                .
                                                                    .
                                     
                                            
                   Specific gravities for C 3 –C 4  are 0.504, 0.63.
                   Inverse form of the correlation is:
                                                                 
                                                         
                                   carbon # =  exp( 15 .129  SG at 20 ° C / ) 7501 , for C5 +
                                                         
                                                                 
                   or
                                                                 . )
                                                      
                                                                     0
                                     carbon # = exp ( (  SG at 20 ° C − 059  / .0661 )
                                                             
                                                      
                                       1.2
                                        1
                                     Density at 20°C, g/cm 3  0.8
                                       0.6
                                       0.4


                                       0.2

                                        0
                                         0     10    20    30    40    50     60
                                                      Carbon Number
                 FIG. 3.7  Correlation for hydrocarbon density vs carbon number.
   54   55   56   57   58   59   60   61   62   63   64